Alkenes And Alcohols Flashcards
What type of mechanism do alkenes undergo
Electrophilic
What happens in an electrophilic addition reaction
C=C attacks electrophile Electrophile bond breaks c=c breaks Half electrophile on one C C+ formed Other half of electrophile attacks c+
What is an electrophile
Electron pair acceptor
Ethene + water –>
Concentrated sulfuric acid catalyst
Alcohol
Test for alkenes
Shake alkene in bromine water
Orange to colourless
Alkene + hydrogen halide –>
Halogenoalkane
Primary carbocation structure
H
|
R-C-H
+
Secondary carbocation structure
R
|
R-C-H
+
Tertiary carbocation structure
R
|
R-C-R
+
Why are tertiary carbocations more stable than primary carbocations
Carbocations with more alkyl groups are more stable because the alkyl groups feed electrons towards the positive charge
What is a substituted alkene
Alkene that’s had a H atom substituted for another atom or group
Dehydration of alcohols mechanism
Lone pair of electrons on the oxygen of the OH group on the alcohol attacks the H+ from the H2SO4 catalyst
The positively charged oxygen pulls electrons away from the carbon. Arrow from C-O goes to O+
H2O molecule leaves creating an unstable carbocation
Arrow goes from H-C to C-C
H is removed and C=C formed