Haber Process Flashcards

1
Q

what is the haber process

A

a reversible reaction between nitrogen and hydrogen to form ammonia

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2
Q

what are the are materials used in the haber process

A

air, natural gas and water

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3
Q

how is nitrogen and hydrogen obtained

A

by the fractional distillation of liquid air - nitrogen

by reacting natural gas with steam - hydrogen

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4
Q

why is ammonia removed from the system as its formed

A

when ammonia is removed, the position of equilibrium moves to the right increasing the yield. Ammonia is removed to prevent the reverse reaction from taking place

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5
Q

why is the unreacted nitrogen and hydrogen recycled

A

to make the process economical and because hydrogen is explosive and highly flammable so must not be released into the atmosphere

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6
Q

why is iron used in the manufacture of ammonia

A

as a catalyst to speed up the rate of reaction

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7
Q

why is the catalyst used often in the form of fine pellets

A

fine pellets have a large surface area so the rate of reaction is faster

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8
Q

what is the chemical equation for the haber process

A

N2 + 3H2 ———–> 2NH3
<———–

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9
Q

is the reaction between nitrogen and hydrogen endothermic or exothermic

A

exothermic

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10
Q

what are the conditions of the haber process

A

temperature of 450 degrees celsius, pressure of 200 atm and an iron catalyst

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11
Q

why is a temperature of 450 degrees celsius used

A

as the forward reaction is exothermic, a low temperature increases the yield of ammonia. However, a low temperature is not used because the rate of reaction is too slow at low temperatures. A high temperature is not used because it moves the position of equilibrium to the left and decreases the yield. So 450 is used as a compromise

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12
Q

why is a pressure of 200 atm used in the haber process

A

a high pressure would shift the position of equilibrium to the right and increase the yield and the pressure but would be too expensive so 200 atm is used as a compromise

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13
Q

why is it expensive to use a high pressure in the haber process

A

high cost of energy needed to generate the pressure
high cost for making pipes and reactors thicker to withstand the pressure
high cost for maintaining the equipment

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14
Q

what are the uses of ammonia

A

make fertilisers such as ammonium nitrate
manufacture nitric acid

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15
Q

what elements are found in fertilisers

A

nitrogen, phosphorous and potassium compounds

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16
Q

why are fertilisers used in agriculture

A

they promote plant growth and increase the yield of crops

17
Q

ammonia + nitric acid =

A

ammonium nitrate

18
Q

what is ammonium nitrate used as

A

fertiliser

19
Q

ammonia + sulfuric acid =

A

ammonium sulfate

20
Q

what is ammonium sulfate

A

a nitrogenous fertiliser

21
Q

what are two advantages of a continuous process compared to a batch process

A

a continuous process happens all the time without stopping so you get a higher yield
a continuous process is easily automated so fewer people need to work on the site