Group II Flashcards
What is the definition of an s-block element
An element which has an atom with the highest energy/outer shell electron in an s subshell
What are he physical properties of group II metals
- atomic radius increases as group descends
- 1st ionisation energetic decreases as you descend group - increased radius and shielding
What is the equation when metal oxides react with water
Metal oxide + water = metal hydroxide
What is the equation when metal oxides react with acid
Metal oxide + acid = salt + water
State two uses of group II compounds
⭕️ MgO - cure indigestion - reacts with excess stomach acid
⭕️ CaCO3 - toothpaste - neutralises acid on teeth
What is a use of calcium carbonate
Makes limewater:
Limestone heated - thermal decomposition to calcium oxide
Calcium oxide mixed with water to form calcium hydroxide (limewater)
What is cement made of
Calcium oxide and silica
What happens when water is added to calcium oxide and silica
Makes calcium silicate
What happens when aluminium oxide reacts with calcium oxide
Makes calcium aluminate
What happens when water evaporates from calcium silicate and calcium aluminate
They crystallise and form solid cement
What is concrete
Cement with gravel and more sand added
What is the equation for the thermal decomposition of metal carbonate
Metal carbonate ➡️ metal oxide + carbon dioxide
What is the trend for decomposition temperature as you descend group II
Increases down group
Why does thermal decomposition temperature increase down group II carbonates and hydroxides
- Size of cation increases
- Charge density decreases
- Cation less able to polarise and destabilise carbonate ion
- therefore more thermally stable
What is the general equation for the decomposition of metal hydroxides
Metal hydroxide ➡️ metal oxide + water