Chemical Equilibria Flashcards

1
Q

What is the definition of reversible

A

A reaction which goes in both forward and backwards directions

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2
Q

What is the definition of equilibrium

A

A reversible reaction in which the amount of each reactant/product remains constant

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3
Q

What is the definition of dynamic equilibrium

A

Rate of forward reaction is equal to the rate of backwards reaction

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4
Q

What are the three characteristics of the equilibrium star

A

Closed system
Both forward and backwards reactions
Dynamic

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5
Q

What are the two types of chemical equilibria

A

Homogeneous and heterogeneous

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6
Q

What is the definition of homogeneous equilibria

A

A reaction in which all the reactants and products are in the same physical state

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7
Q

What is the definition of heterogeneous equilibria

A

A reaction in which all the reactants and products are not in the same physical state

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8
Q

What is the equilibrium constant

A

Kc = [products]
—————
[reactants]

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9
Q

What does the number of moles in the equation represent in the equilibrium constant

A

The power

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10
Q

What does the equilibrium constant indicate and what is the only thing it depends on

A

Indicates how far the equilibrium is over to the rhs

Depends on temperature

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11
Q

What is Le Chatelier’s Principle

A

When a change is imposed on a system in equilibrium the system tends to adjust so as to minimise the change

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12
Q

What does the position of equilibrium mean

A

Proportion of reactants and products in the equilibrium system

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13
Q

What does a large Kc indicate

A

The position of equilibrium is to the rhs

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14
Q

What does a low Kc indicate

A

The position of equilibrium is to the lhs

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15
Q

How do you know when equilibrium has been achieved

A

Colour stays the same

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16
Q

What effect does a change in pressure have on solid liquid and gas

A

No effect in solid or liquid

In gas it moves to side with fewer molecules - if number of moles is the same then no effect on equilibrium

17
Q

What effect does increase and decrease in temp have on the position of equilibrium

A

⭕️ Increase - shift in direction of endothermic process

⭕️ Decrease - shift in direction of exothermic process

18
Q

What effect does a change in concentration have on the position of equilibrium

A

⭕️ Increase reactants - shift to rhs

⭕️ Increase products - shift to lhs

19
Q

What effect does the presence of a catalyst on the position of equilibrium

A

No effect on position

20
Q

What is the equation and conditions for the Haber process

A
See notes for equation 
Conditions:
- 450°C - compromise temp
- 200atm - favour NH3 production 
- iron catalyst - equilibrium attained more quickly
21
Q

What is the equation for the contact process

A
See notes for equation 
Conditions:
- 450°C - compromise temp 
- 2atm - favour SO3 production
- V2O5 catalyst - equilibrium attained more quickly