Group 7 - Halogens Flashcards

1
Q

Physical Properties of Halogens

A
  • F₂ and Cl₂ are gases at room temperature (F₂ is a pale yellow gas and Cl₂ is a greenish gas
  • Bromine is a red-brown liquid at room temperature
  • Iodine is a black solid at room temperature
  • All halogens have the characteristic ‘swimming pool’ smell
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2
Q

Atomic Radius Down Group 7

A
  • Increases
  • Nuclear charge increases
  • Shielding increases
  • Weaker attraction between the nucleus and the outer shell electrons
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3
Q

Electronegativity Down Group 7

A
  • Decreases
  • Nuclear charge increases
  • Shielding increases
  • Less attraction between the nucleus and the bonding pair of electrons
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4
Q

Melting and Boiling Points Down Group 7

A
  • Increases
  • More electrons means stronger van der waals forces
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5
Q

Oxidising Ability of Halogens Down Group 7

A
  • Decreases
  • Fluorine is the strongest oxidising agent
  • This is because it has the highest electronegativity so it can easily gain electrons
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6
Q

Reducing Ability of Halide Ions Down Group 7

A
  • Increases
  • Fluoride Ions are the weakest reducing agent
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7
Q

Displacement Reactions

A

When a more reactive element displaces a less reactive element within a compound during a chemical reaction

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8
Q

Sodium Chloride and Sulfuric Acid Reaction

A
  • Sodium Chloride + Sulfuric Acid –> Sodium Hydrogensulfate + HCL gas
  • NaCl(s) + H₂ SO₄(l) –> Na₂ HSO₄(s) + HCL(g)
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9
Q

Sodium Bromide and Sulfuric Acid Reaction

A
  • Sodium Bromide + Sulfuric Acid –> Sodium Hydrogensulfate + HBr gas
  • NaBr(s) + H₂ SO₄ –> Na₂ HSO₄(s) + HBr(g)
  • Br is a better reducing agent than Cl so HBr separates into ions and reduces H₂ SO₄ into SO₂
  • 2H+ + 2Br- + H₂SO₄(l) –> SO +
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