Green chemistry Flashcards

1
Q

The chemical industry has a significant positive impact on our daily lives, producing substances that we use every day. However, scientists must ensure that the negative impact on the environment and society is minimised, through careful research into ‘green chemistry’.

The chemical industry

Bulk and fine chemicals

The chemical industry makes some chemicals in very large quantities. These chemicals are called bulk chemicals. Examples of these include:

ammonia

sulfuric acid

sodium hydroxide

phosphoric acid

Bulk chemicals are made at large chemical plants

Other chemicals are made in much smaller quantities, and are called fine chemicals. Examples of these include:

drugs

food additives

fragrances

Research and development

A large proportion of the people employed in the chemical industry work in research and development.

Developing new chemical products or processes – such as new catalysts for industrial reactions - requires an extensive programme of research and development.

The government has a duty to protect people working in the chemical industry, and also to protect the consumers and the environment. It imposes strict regulations on the chemical industry to control the manufacturing processes as well as the storage and processing of chemicals.

A

The chemical industry has a significant positive impact on our daily lives, producing substances that we use every day. However, scientists must ensure that the negative impact on the environment and society is minimised, through careful research into ‘green chemistry’.

The chemical industry

Bulk and fine chemicals

The chemical industry makes some chemicals in very large quantities. These chemicals are called bulk chemicals. Examples of these include:

ammonia

sulfuric acid

sodium hydroxide

phosphoric acid

Bulk chemicals are made at large chemical plants

Other chemicals are made in much smaller quantities, and are called fine chemicals. Examples of these include:

drugs

food additives

fragrances

Research and development

A large proportion of the people employed in the chemical industry work in research and development.

Developing new chemical products or processes – such as new catalysts for industrial reactions - requires an extensive programme of research and development.

The government has a duty to protect people working in the chemical industry, and also to protect the consumers and the environment. It imposes strict regulations on the chemical industry to control the manufacturing processes as well as the storage and processing of chemicals.

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2
Q

Give examples of bulk chemicals that the chemical industry produces?

A

The chemical industry

Bulk and fine chemicals

The chemical industry makes some chemicals in very large quantities. These chemicals are called bulk chemicals. Examples of these include:

ammonia

sulfuric acid

sodium hydroxide

phosphoric acid

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3
Q

Other chemicals are made in much smaller quantities, and are called ……….. chemicals. Examples of these include ?

A

Other chemicals are made in much smaller quantities, and are called fine chemicals. Examples of these include:

drugs

food additives

fragrances

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4
Q

A large proportion of the people employed in the chemical industry work in research and development.
Why?

A

Developing new chemical products or processes – such as new catalysts for industrial reactions - requires an extensive programme of research and development.

The government has a duty to protect people working in the chemical industry, and also to protect the consumers and the environment. It imposes strict regulations on the chemical industry to control the manufacturing processes as well as the storage and processing of chemicals.

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5
Q

What are Catalysts?

A

Catalysts

Chemists are always interested in finding new catalysts for industrial reactions in order to save money. Catalysts speed up chemical reactions without being used up or chemically changed.

A catalyst might be expensive to purchase. But because they are reused, they save money in the long term and can help to make processes more sustainable

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6
Q

Some processes use catalysts that are ?

A

Some processes use catalysts that are enzymes. This often means that the process needs to take place at an optimum temperature and pH. If the temperature is too high, enzymes can denature and no longer work.

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7
Q

How does a catalyst work ?

A

A catalyst works by providing an alternative route for a reaction with a lower activation energy. The activation energy is the amount of energy needed to break bonds in the reactants in order to start a chemical reaction

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8
Q

What is green chemistry?

A

Green chemistry is a term that is used to describe a set of principles that can help to make the production of a chemical more sustainable.

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9
Q

The sustainability of a process depends on 7 factors? What are they?

A

whether or not the raw materials needed are renewable

the ‘atom economy’ (the total mass of the atoms in the desired product expressed as a percentage of the total mass of all the atoms in all of the reactants)

whether there are a lot of waste products (or by-products) and whether they can be recycled, used for something else, or are hazardous

the amount of energy that is required by the process or released from the process

the overall effect of the process on the environment

whether the process is hazardous for the workers

the social and economic benefits

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10
Q

Chemical plants manufacture chemicals. Where do reactions take place that convert reactants into products.

A

The centre of the plant is where reactions take place that convert reactants into products.

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11
Q

The chemical(s) fed into the process are known as what? Sometimes they have to be ….. ?

A

The chemical(s) fed into the process (known as the ‘feedstock’) may sometimes have to be heated, which takes energy. Synthesis then takes place inside the reactor often with the presence of a catalyst.

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12
Q

where does synthesis take place and what presence is needed in synthesis?

A

A mixture of chemicals that needs to be separated then leaves the reactor. This separation of products isolates the desired product from by-products and unchanged starting materials. Unchanged starting materials may be recycled and fed back into the reactor to make the process more sustainable.

The sustainability of
heated, which takes energy. Synthesis then takes place inside the reactor often with the presence of a catalyst.

A mixture of chemicals that needs to be separated then leaves the reactor. This separation of products isolates the desired product from by-products and unchanged starting materials. Unchanged starting materials may be recycled and fed back into the reactor to make the process more sustainable.

Synthesis then takes place inside the reactor often with the presence of a catalyst.

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13
Q

A mixture of chemicals that needs to be separated then leaves the reactor. What does this separation of products do?

A

A mixture of chemicals that needs to be separated then leaves the reactor. This separation of products isolates the desired product from by-products and unchanged starting materials. Unchanged starting materials may be recycled and fed back into the reactor to make the process more sustainable.

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14
Q

The periodic table can be used to find out ………… ………. …………of an element. What is Nitrogen’s relative atomic mass?

A

The periodic table can be used to find out the relative atomic mass of an element. Nitrogen’s relative atomic mass is 14 (the number 7 is the atomic number).

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15
Q

How is the relative formula mass (RFM) of a compound calculated ?

A

The relative formula mass (RFM) of a compound is calculated by adding up all of the relative atomic masses of the atoms that it contains.

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16
Q

ammonium nitrate has the formula of ?

The compound contains ? nitrogen atoms, ? hydrogen atoms and ? oxygen atoms.

A

ammonium nitrate has the formula NH4NO3. The compound contains two nitrogen atoms, four hydrogen atoms and three oxygen atoms.

17
Q

So the calcution for its relative formula mass of ammonium nitrate is:

(2 x 14) + (4 x 1) + (3 x 16) = 80

If the formula of a compound has brackets, that part should be worked out first. It can then be multiplied by the number after the brackets, before adding on the other parts.

A

(2 x 14) + (4 x 1) + (3 x 16) = 80

If the formula of a compound has brackets, that part should be worked out first. It can then be multiplied by the number after the brackets, before adding on the other parts.

18
Q

For example, ammonium sulfate has the formula ? Its relative formula mass is:

A

For example, ammonium sulfate has the formula (NH4)2SO4.

Its relative formula mass is:

(NH4) = 14 + (4 x 1) = 18

(NH4)2 = 18 x 2 = 36

(NH4)2SO4 = 36 + 32 + (4 x 16) = 132

19
Q

How are masses calculated using a balanced symbol equation ?

A

A balanced symbol equation can be interpreted quantitatively as long as the relative formula masses (RFMs) have been calculated. It is then simply a question of manipulating a ratio.

20
Q

For example, in the thermal decomposition of calcium carbonate, how do we work out the mass of calcium oxide that can be produced when 300 tonnes of calcium carbonate is heated?

A

For example, in the thermal decomposition of calcium carbonate, we can work out the mass of calcium oxide that can be produced when 300 tonnes of calcium carbonate is heated: