Glassware Flashcards
Composition of glassware
-mixture of silica from fine sand or pulverized sandstone
-alkali (soda/potash -finer)to lower mp
-stabilizer, lime
-Cullet,assist melting mixture
Properties
Varies according to adding of following in oxide form:
Lead
Boron
Barium
Cerium
Metallic acids
Mn
Uses of oxides used in glassware
Lead-brilliance &weight
Boron-thermal &electrical resistance
Ba-^ refractive index
Cerium-absorb infracted rays
Metallic oxides-impart color
Mn-decolorising
Types of glassware
Hard(borosilicate)-common
Soft (soda lime)
Ingredients of hard glassware
(BASS)
Silica-80.6%
Boric oxide-12.6%
Sodium oxide-4.15%
Al oxide-2.2%
Properties of hard
Heat resistant
Chemical resistant
Withstand mechanical stress
Preparation of beakers nd glassware for heating
Expensive
Features of soft /sodalime glasswares
-high alkali composition
-free soda present in sodalime, neutralised before use
Less resistant to thermal &mechanical shock
-cheaper than hard
-ideal for storage of reagents
-easy to bend and break
-used to make Pasteur pipette and other glassware
-low cost
-easily available
-poor resistant to heat
Varieties of glassware
Corex -6 times stronger than hard
Alkali resistant -thermal resistance
Lead oxide
Ground
Bottle
Low actinic
Fused silica
Alumino silicate
Grades of glassware
Hard glass
Borosilicate glass
Heat resistant Borosilicate -widely used,pyrex glass
Low alkali Borosilicate
Class A-high accuracy
Class B-when accuracy is not critical
Specially treated -acid washed
Specially washed -coated with silicon, Teflon,other coatings inside
Composition of aluminosilicate
Silica-57%
Alumina-16%
Boric acid-4%
Barium oxide-6%
Mg-7%
Lime-10%
Composition of lead oxide
Silica-59%
Soda (na2o)-2%
Lead oxide-25%
K2o-12%
Alumina-0.4%
Zinc oxide-1.5%