Gibbs Free Energy Flashcards

1
Q

The combination of a system’s enthalpy and entropy is called what?

A

Gibbs free energy

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2
Q

What is the formula for change in Gibbs free energy?

A

ΔG = ΔH - TΔS

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3
Q

What does free energy change (ΔG) measure?

A

The spontaneity of a process and the useful energy available from it

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4
Q

If ΔG is positive, is the process spontaneous?

A

No, it is spontaneous in the reverse direction

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5
Q

If ΔG is negative, is the process spontaneous?

A

Yes

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6
Q

If ΔG = 0, is the process spontaneous?

A

The system is at equilibrium

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7
Q

If ΔH is negative and ΔS is positive, when is the reaction spontaneous?

A

Always

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8
Q

If ΔH is positive and ΔS is negative, when is the reaction spontaneous?

A

Never

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9
Q

For ΔG = ΔH - TΔS, at a low temperature, is enthalpy or entropy change more important?

A

ΔH

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10
Q

For ΔG = ΔH - TΔS, at a high temperature, is enthalpy or entropy change more important?

A

ΔS

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11
Q

What is the difference between ΔG and ΔG°?

A

ΔG° is when Q = 1

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12
Q

What is the equation for ΔG using Q and K?

A

ΔG = RT ln(Q/K)

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13
Q

What is the equation for ΔG° using K?

A

ΔG° = -RT ln(K)

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14
Q

What is the equation for ΔG using ΔG° and Q?

A

ΔG = ΔG° + RT ln(Q)

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