Gibbs Free Energy Flashcards
The combination of a system’s enthalpy and entropy is called what?
Gibbs free energy
What is the formula for change in Gibbs free energy?
ΔG = ΔH - TΔS
What does free energy change (ΔG) measure?
The spontaneity of a process and the useful energy available from it
If ΔG is positive, is the process spontaneous?
No, it is spontaneous in the reverse direction
If ΔG is negative, is the process spontaneous?
Yes
If ΔG = 0, is the process spontaneous?
The system is at equilibrium
If ΔH is negative and ΔS is positive, when is the reaction spontaneous?
Always
If ΔH is positive and ΔS is negative, when is the reaction spontaneous?
Never
For ΔG = ΔH - TΔS, at a low temperature, is enthalpy or entropy change more important?
ΔH
For ΔG = ΔH - TΔS, at a high temperature, is enthalpy or entropy change more important?
ΔS
What is the difference between ΔG and ΔG°?
ΔG° is when Q = 1
What is the equation for ΔG using Q and K?
ΔG = RT ln(Q/K)
What is the equation for ΔG° using K?
ΔG° = -RT ln(K)
What is the equation for ΔG using ΔG° and Q?
ΔG = ΔG° + RT ln(Q)