General Chemistry Flashcards

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1
Q

What molecules are soluble in aqueous solution?

A
  1. Alkali metals
  2. Ammonium
  3. Chlorate ClO3-, perchlorate ClO42-, nitrate, and acetate
  4. Cl-, Br-, I- (not Ag+, Pb2+, Hg2+)
  5. SO42- (not Ba2+, Sr2+, Ca2+, Pb2+, Hg(II)(III), Ca2+, Ag2+)
  6. Alkali hydrides and Ba(OH)2, Sr(OH)2, and Ca(OH)2
  7. S2- group IA and IIA
  8. Not SO32-, CO32-, CrO42-, PO43- (except NH4+ and Grp IA)
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2
Q

What is the ionization constant?

A

Ka=[H+][A-]/[HA]

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3
Q

How do you find the pH of a buffer solution?

A

pH=pKa+log[A-]/[HA]

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4
Q

What is the principle quantum number?

A

n, which tells us the energy level of the shells. As we get further away from the nucleus, there is an increase in E.

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5
Q

What is the Azimuthal number?

A

L, which tells us the shells or angular orbital shape. s, p, d, and f. 4l+2=electrons.

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6
Q

What is the magnetic quantum number?

A

M (sub L), which tells us how many electrons are in each orbital. No more than 2 per. -L to L, including zero.

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7
Q

What is the spin quantum number?

A

-1/2 and +1/2.

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8
Q

How do you determine the E level of an electron configuration?

A

E=n+L

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9
Q

How do you determine the energy emitted from an electron?

A

E=hf (h planck’s constant and f frequency). Note: c/wavelength=f.

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10
Q

When an electron is excited from ground state to an excited state, is energy absorbed or emitted?

A

Energy is absorbed.

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11
Q

In chemistry, the dipole arrow points from +–>- or - –> +?

The equation?

A

+—->-

u=qr q-colombs

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12
Q

An strong acid and a strong base react, what happens?

A

Neutralization rxn, which produces H2O and a salt.

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13
Q

What is acetate, cyanide, permanganate, nitrate, chlorate, sulfate, carbonate, phosphate, chromate, dichromate, peroxide, thiocyanide, and thiosulfate?

A

CH3COO-, CN-, MnO4-, NH3-, ClO3-, SO42-, CO32-, PO43-, CrO42-, Cr2O72-, O22-, SCN-, and S2O32-

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14
Q

What are the bonding electrons?

A

Valence electrons

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15
Q

Exceptions of the octet rule

A

beyond period 3. They have d orbitals.

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16
Q

Coordinate covalent bond

A

When the electrons come from one atom

17
Q

What atom goes in the center in bonding?

A

The least electronegative atom (not H).

18
Q

What are the van der Waals interactions?

A

London dispersion forces and dipole-dipole interactions.

19
Q

Avogadro’s number

A

6.02x10^23 neutrons and protons to equal X g.

20
Q

Types of chemical reactions

A

Combination rxn, decomposition rxn, single-displacement rxn (redox), and double-displacement rxn (metathesis)

21
Q

What is the energy barrier for a reaction to proceed?

A

Activation energy (Ea)

22
Q

What is the equilibrium constant?

A

Kc=[Products]^P/[Reactants]^R. Solids and liquids to not appear.

23
Q

Le Chatlier’s Principle

A

Equilibrium will shift when stressor is given to system. Temperature, pressure, volume, or concentration.

24
Q

How does temperature change equilibrium constants?

A

In exothermic reactions, think of heat as a product. Endothermic reactions, think of it as a reactant.

25
Q

Specific heat equation

A

Q=mcdT

26
Q

Bond breakage takes or releases energy?

A

It is an endothermic process.

27
Q

Entropy equation

A

S=qrev/T