GDQ2 Flashcards

1
Q

what has no reaction in nitration test

A

aliphatics

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2
Q

what gives positive reaction in bromine test

A

unsaturated

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3
Q

what gives positive reaction in potassium permanganate test

A

unsaturated

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4
Q

what gives positive reaction in nitration test

A

aromatics

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5
Q

why does aromatics give positive in nitration test

A

nitrations are performed in a mixture of concentrated nitric and concentrated sulfuric acids = generates the nitronium ion = active electrophile attacked by the aromatic ring

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6
Q

why does unsaturated give positive result in potassium permanganate test

A

can oxidize carbon atoms with weak bonds such as double and triple bonds

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7
Q

why does unsaturated give positive result in bromine test

A

bromine reacts with alkenes by disrupting the carbon-carbon double bond and adding bromine atoms to the hydrocarbon

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8
Q

does aromatics give a positive reaction in bromine test

A

no (there is no reaction)

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9
Q

what gives a no reaction in potassium permanganate test

A

nonalkylated

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10
Q

what gives a positive reaction in potassium permanganate test

A

alkylated

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11
Q

principle of nitration test

A

nitration of aromatics

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12
Q

purpose of nitration test

A

to distinguish between aromatics and aliphatics

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13
Q

is nitration test a specific test for aromatics or a general test

A

a specific test for aromatics

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14
Q

positive visible result of nitration test

A

yellow oil

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15
Q

principle of bromine test

A

halogenation reaction via addition

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16
Q

purpose of bromine test

A

test for unsaturation

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17
Q

color reagent of bromine

A

bromine water (color:orange)

18
Q

positive visible result of bromine

A

decolorization of bromine

19
Q

principle of potassium permanganate test

A

oxidation

20
Q

purpose of potassium permanganate test

A

test for unsaturation or func groups that can be oxidized

21
Q

reagent of potassium permanganate test

A

purple

22
Q

other name of dichromate test

A

jones oxidation test

23
Q

principle of dichromate test

A

oxidation reaction

24
Q

purpose of dichromate test

A

to classify alcohols based on their oxidation reaction

25
Q

reagents of dichromate test

A

potassium dichromate and sulfuric acid

26
Q

principle of DNPH test

A

condensation reaction

27
Q

purpose of DNPH test

A

test for presence of aldehydes and ketones

28
Q

positive visible result of DNPH test

A

yellow ppt

29
Q

purpose of iodoform test

A

presence of an aldehyde or ketone

30
Q

positive visible result of iodoform test

A

yellow ppt

31
Q

principle of lucas test

A

substitution

32
Q

purpose of lucas test

A

to classify primary, secondary and tertiary alcohols

33
Q

positive visible result of lucas test

A

cloudiness

34
Q

reagents of lucas test

A

zinc chloride and conc. HCI

35
Q

principle of tollens test

A

mild oxidation reaction

36
Q

purpose of tollen’s test

A

to identify aldehydes

37
Q

tollen’s reagent

A

ammonium hydroxide and silver nitrate solution

38
Q

positive visible result

A

silver coat lining

39
Q

principle of hydroxamic test

A

complexation

40
Q

purpose of hydroxamic test

A

to identify a ester

41
Q

positive visible result

A

magenta red solution