Further organic synthesis Flashcards by Rosie Johnson

Q

ALKANE -> HALOALKANE

A

Halogen and UV light

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Q

ALKANE -> HALOALKANE
reaction

A

Free radical substitution

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Q

HALOALKANE -> ALCOHOL

A

NaOH and heat under reflux

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Q

HALOALKANE -> ALCOHOL
reaction

A

Nucleophilic substitution

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Q

ALCOHOL -> HALOALKANE

A

Sodium halide & H2SO4
Heat under reflux

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Q

ALCOHOL -> HALOALKANE
reaction

A

Nucleophilic substitution

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Q

PRIMARY ALCOHOL -> ALDEHYDE

A

K2Cr2O7 & H2SO4
distill

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Q

PRIMARY ALCOHOL -> ALDEHYDE
reaction

A

Oxidation

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Q

ALDEHYDE -> PRIMARY ALCOHOL

A

NaBH4 & H2O

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Q

ALDEHYDE -> PRIMARY ALCOHOL
reaction

A

Reduction

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Q

PRIMARY ALCOHOL -> CARBOXYLIC ACID

A

K2Cr2O7 & H2SO4
heat under reflux

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Q

PRIMARY ALCOHOL -> CARBOXYLIC ACID
reaction

A

Oxidation

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Q

ALDEHYDE -> CARBOXYLIC ACID

A

K2Cr2O7 & H2SO4
heat under reflux

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Q

ALDEHYDE -> CARBOXYLIC ACID
reaction

A

Oxidation

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Q

CARBOXYLIC ACID -> ACYL CHLORIDE

A

SOCl2

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Q

CARBOXYLIC ACID -> ACYL CHLORIDE
reaction

A

Chlorination

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Q

ACYL CHLORIDE -> CARBOXYLIC ACID

A

H2O

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Q

ACYL CHLORIDE -> CARBOXYLIC ACID
reaction

A

Hydrolysis

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Q

ACYL CHLORIDE -> PRIMARY AMIDE

A

NH3

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Q

ACYL CHLROIDE -> PRIMARY AMIDE
reaction

A

Nucleophilic addition elimination

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Q

ACYL CHLORIDE -> SECONDARY AMIDE

A

Primary amine

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Q

ACYL CHLORIDE -> SECONDARY AMIDE
reaction

A

Nucleophilic addition elimination

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Q

ALKENE -> ALKANE

A

H2 and nickel catalyst
150 degrees

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Q

ALKENE -> ALKANE
reaction

A

Hydration

Q

ALKENE -> HALOALKANE

A

Hydrogen halide

Q

ALKENE -> HALOALKANE
reaction

A

Electrophilic addition

Q

HALOALKANE -> NITRILE

A

NaCN & ethanol

Q

HALOALAKNE -> NITRILE
reaction

A

Nucleophilic substitution

Q

HALOALKANE -> AMINE

A

NH3 & ethanol

Q

HALOALKANE -> AMINE
reaction

A

Nucleophilic substitution

Q

NITRILE -> AMINE

A

H2 & Ni

Q

HYDROXYNITRILE -> AMINE

A

H2 & Ni

Q

NITRILE or HYDROXYNITRILE -> CARBOXYLIC ACID

A

H2O & HCl
Heat

Q

NITRILE or HYDROXYNITRILE -> CARBOXYLIC ACID
reaction

A

Hydrolysis

Q

SECONDARY ALCOHOL -> KETONE

A

K2Cr2O7 & H2SO4
Heat under reflux

Q

SECONDARY ALCOHOL -> KETONE
reaction

A

Oxidation

Q

KETONE -> SECONDARY ALCOHOL

A

NaBH4 & H2O

Q

KETONE -> SECONDARY ALCOHOL
reaction

A

Reduction

Q

ALKENE -> ALCOHOL

A

H2SO4 & steam
Heat

Q

ALKENE -> ALCOHOL
reaction

A

Hydration

Q

ALCOHOL -> ALKENE

A

H2SO4 or H3PO4

Q

ALCOHOL -> ALKENE
reaction

A

Dehydration

Q

ALCOHOL -> ESTER

A

Carboxylic acid & conc H2SO4

Q

ALCOHOL -> ESTER
reaction

A

Esterification

Q

KETONE -> HYDROXYNITRILE

A

NaCN & H+ (aq)

Q

ALDEHYDE -> HYDROXYNITRILE

A

NaCN & H+(aq)

Q

ALDEHYDE -> HYDROXYNITRILE
reaction

A

Nucleophilic addition

Q

CARBOXYLIC ACID -> ESTER

A

Alcohol & H2SO4

Q

CARBOXYLIC ACID -> ESTER
reaction

A

Esterification

Q

ESTER -> CARBOXYLIC ACID

A

Dilute acid
Heat

Q

ESTER -> CARBOXYLIC ACID
reaction

A

Acid hydrolysis

Q

ESTER -> CARBOXYLATE

A

NaOH (OH-)

Q

ESTER -> CARBOXYLATE
reaction

A

Alkaline hydrolysis

Q

ACYL CHLORIDE -> ESTER

A

Alcohol

Q

ACYL CHLORIDE -> PRIMARY AMIDE

A

NH3

Q

ACYL CHLORIDE -> PRIMARY AMIDE
reaction

A

Nucleophilic addition elimination

Q

ACYL CHLORIDE -> SECONDARY AMIDE

A

Primary amine

Q

ACYL CHLORIDE -> SECONDARY AMIDE
reaction

A

Nucleophilic addition elimination