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A-Level Chemistry > Further organic synthesis > Flashcards

Further organic synthesis Flashcards

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1
Q

ALKANE -> HALOALKANE

A

Halogen and UV light

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2
Q

ALKANE -> HALOALKANE
reaction

A

Free radical substitution

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3
Q

HALOALKANE -> ALCOHOL

A

NaOH and heat under reflux

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4
Q

HALOALKANE -> ALCOHOL
reaction

A

Nucleophilic substitution

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5
Q

ALCOHOL -> HALOALKANE

A

Sodium halide & H2SO4
Heat under reflux

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6
Q

ALCOHOL -> HALOALKANE
reaction

A

Nucleophilic substitution

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7
Q

PRIMARY ALCOHOL -> ALDEHYDE

A

K2Cr2O7 & H2SO4
distill

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8
Q

PRIMARY ALCOHOL -> ALDEHYDE
reaction

A

Oxidation

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9
Q

ALDEHYDE -> PRIMARY ALCOHOL

A

NaBH4 & H2O

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10
Q

ALDEHYDE -> PRIMARY ALCOHOL
reaction

A

Reduction

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11
Q

PRIMARY ALCOHOL -> CARBOXYLIC ACID

A

K2Cr2O7 & H2SO4
heat under reflux

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12
Q

PRIMARY ALCOHOL -> CARBOXYLIC ACID
reaction

A

Oxidation

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13
Q

ALDEHYDE -> CARBOXYLIC ACID

A

K2Cr2O7 & H2SO4
heat under reflux

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14
Q

ALDEHYDE -> CARBOXYLIC ACID
reaction

A

Oxidation

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15
Q

CARBOXYLIC ACID -> ACYL CHLORIDE

A

SOCl2

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16
Q

CARBOXYLIC ACID -> ACYL CHLORIDE
reaction

A

Chlorination

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17
Q

ACYL CHLORIDE -> CARBOXYLIC ACID

A

H2O

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18
Q

ACYL CHLORIDE -> CARBOXYLIC ACID
reaction

A

Hydrolysis

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19
Q

ACYL CHLORIDE -> PRIMARY AMIDE

A

NH3

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20
Q

ACYL CHLROIDE -> PRIMARY AMIDE
reaction

A

Nucleophilic addition elimination

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21
Q

ACYL CHLORIDE -> SECONDARY AMIDE

A

Primary amine

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22
Q

ACYL CHLORIDE -> SECONDARY AMIDE
reaction

A

Nucleophilic addition elimination

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23
Q

ALKENE -> ALKANE

A

H2 and nickel catalyst
150 degrees

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24
Q

ALKENE -> ALKANE
reaction

A

Hydration

25
Q

ALKENE -> HALOALKANE

A

Hydrogen halide

26
Q

ALKENE -> HALOALKANE
reaction

A

Electrophilic addition

27
Q

HALOALKANE -> NITRILE

A

NaCN & ethanol

28
Q

HALOALAKNE -> NITRILE
reaction

A

Nucleophilic substitution

29
Q

HALOALKANE -> AMINE

A

NH3 & ethanol

30
Q

HALOALKANE -> AMINE
reaction

A

Nucleophilic substitution

31
Q

NITRILE -> AMINE

A

H2 & Ni

32
Q

HYDROXYNITRILE -> AMINE

A

H2 & Ni

33
Q

NITRILE or HYDROXYNITRILE -> CARBOXYLIC ACID

A

H2O & HCl
Heat

34
Q

NITRILE or HYDROXYNITRILE -> CARBOXYLIC ACID
reaction

A

Hydrolysis

35
Q

SECONDARY ALCOHOL -> KETONE

A

K2Cr2O7 & H2SO4
Heat under reflux

36
Q

SECONDARY ALCOHOL -> KETONE
reaction

A

Oxidation

37
Q

KETONE -> SECONDARY ALCOHOL

A

NaBH4 & H2O

38
Q

KETONE -> SECONDARY ALCOHOL
reaction

A

Reduction

39
Q

ALKENE -> ALCOHOL

A

H2SO4 & steam
Heat

40
Q

ALKENE -> ALCOHOL
reaction

A

Hydration

41
Q

ALCOHOL -> ALKENE

A

H2SO4 or H3PO4

42
Q

ALCOHOL -> ALKENE
reaction

A

Dehydration

43
Q

ALCOHOL -> ESTER

A

Carboxylic acid & conc H2SO4

44
Q

ALCOHOL -> ESTER
reaction

A

Esterification

45
Q

KETONE -> HYDROXYNITRILE

A

NaCN & H+ (aq)

46
Q

ALDEHYDE -> HYDROXYNITRILE

A

NaCN & H+(aq)

47
Q

ALDEHYDE -> HYDROXYNITRILE
reaction

A

Nucleophilic addition

48
Q

CARBOXYLIC ACID -> ESTER

A

Alcohol & H2SO4

49
Q

CARBOXYLIC ACID -> ESTER
reaction

A

Esterification

50
Q

ESTER -> CARBOXYLIC ACID

A

Dilute acid
Heat

51
Q

ESTER -> CARBOXYLIC ACID
reaction

A

Acid hydrolysis

52
Q

ESTER -> CARBOXYLATE

A

NaOH (OH-)

53
Q

ESTER -> CARBOXYLATE
reaction

A

Alkaline hydrolysis

54
Q

ACYL CHLORIDE -> ESTER

A

Alcohol

55
Q

ACYL CHLORIDE -> PRIMARY AMIDE

A

NH3

56
Q

ACYL CHLORIDE -> PRIMARY AMIDE
reaction

A

Nucleophilic addition elimination

57
Q

ACYL CHLORIDE -> SECONDARY AMIDE

A

Primary amine

58
Q

ACYL CHLORIDE -> SECONDARY AMIDE
reaction

A

Nucleophilic addition elimination

A-Level Chemistry (42 decks)

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