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A-Level Chemistry > Further organic synthesis > Flashcards

Further organic synthesis Flashcards

1
Q

ALKANE -> HALOALKANE

A

Halogen and UV light

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2
Q

ALKANE -> HALOALKANE
reaction

A

Free radical substitution

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3
Q

HALOALKANE -> ALCOHOL

A

NaOH and heat under reflux

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4
Q

HALOALKANE -> ALCOHOL
reaction

A

Nucleophilic substitution

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5
Q

ALCOHOL -> HALOALKANE

A

Sodium halide & H2SO4
Heat under reflux

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6
Q

ALCOHOL -> HALOALKANE
reaction

A

Nucleophilic substitution

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7
Q

PRIMARY ALCOHOL -> ALDEHYDE

A

K2Cr2O7 & H2SO4
distill

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8
Q

PRIMARY ALCOHOL -> ALDEHYDE
reaction

A

Oxidation

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9
Q

ALDEHYDE -> PRIMARY ALCOHOL

A

NaBH4 & H2O

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10
Q

ALDEHYDE -> PRIMARY ALCOHOL
reaction

A

Reduction

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11
Q

PRIMARY ALCOHOL -> CARBOXYLIC ACID

A

K2Cr2O7 & H2SO4
heat under reflux

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12
Q

PRIMARY ALCOHOL -> CARBOXYLIC ACID
reaction

A

Oxidation

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13
Q

ALDEHYDE -> CARBOXYLIC ACID

A

K2Cr2O7 & H2SO4
heat under reflux

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14
Q

ALDEHYDE -> CARBOXYLIC ACID
reaction

A

Oxidation

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15
Q

CARBOXYLIC ACID -> ACYL CHLORIDE

A

SOCl2

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16
Q

CARBOXYLIC ACID -> ACYL CHLORIDE
reaction

A

Chlorination

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17
Q

ACYL CHLORIDE -> CARBOXYLIC ACID

A

H2O

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18
Q

ACYL CHLORIDE -> CARBOXYLIC ACID
reaction

A

Hydrolysis

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19
Q

ACYL CHLORIDE -> PRIMARY AMIDE

A

NH3

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20
Q

ACYL CHLROIDE -> PRIMARY AMIDE
reaction

A

Nucleophilic addition elimination

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21
Q

ACYL CHLORIDE -> SECONDARY AMIDE

A

Primary amine

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22
Q

ACYL CHLORIDE -> SECONDARY AMIDE
reaction

A

Nucleophilic addition elimination

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23
Q

ALKENE -> ALKANE

A

H2 and nickel catalyst
150 degrees

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24
Q

ALKENE -> ALKANE
reaction

25
ALKENE -> HALOALKANE
Hydrogen halide
26
ALKENE -> HALOALKANE reaction
Electrophilic addition
27
HALOALKANE -> NITRILE
NaCN & ethanol
28
HALOALAKNE -> NITRILE reaction
Nucleophilic substitution
29
HALOALKANE -> AMINE
NH3 & ethanol
30
HALOALKANE -> AMINE reaction
Nucleophilic substitution
31
NITRILE -> AMINE
H2 & Ni
32
HYDROXYNITRILE -> AMINE
H2 & Ni
33
NITRILE or HYDROXYNITRILE -> CARBOXYLIC ACID
H2O & HCl Heat
34
NITRILE or HYDROXYNITRILE -> CARBOXYLIC ACID reaction
Hydrolysis
35
SECONDARY ALCOHOL -> KETONE
K2Cr2O7 & H2SO4 Heat under reflux
36
SECONDARY ALCOHOL -> KETONE reaction
Oxidation
37
KETONE -> SECONDARY ALCOHOL
NaBH4 & H2O
38
KETONE -> SECONDARY ALCOHOL reaction
Reduction
39
ALKENE -> ALCOHOL
H2SO4 & steam Heat
40
ALKENE -> ALCOHOL reaction
Hydration
41
ALCOHOL -> ALKENE
H2SO4 or H3PO4
42
ALCOHOL -> ALKENE reaction
Dehydration
43
ALCOHOL -> ESTER
Carboxylic acid & conc H2SO4
44
ALCOHOL -> ESTER reaction
Esterification
45
KETONE -> HYDROXYNITRILE
NaCN & H+ (aq)
46
ALDEHYDE -> HYDROXYNITRILE
NaCN & H+(aq)
47
ALDEHYDE -> HYDROXYNITRILE reaction
Nucleophilic addition
48
CARBOXYLIC ACID -> ESTER
Alcohol & H2SO4
49
CARBOXYLIC ACID -> ESTER reaction
Esterification
50
ESTER -> CARBOXYLIC ACID
Dilute acid Heat
51
ESTER -> CARBOXYLIC ACID reaction
Acid hydrolysis
52
ESTER -> CARBOXYLATE
NaOH (OH-)
53
ESTER -> CARBOXYLATE reaction
Alkaline hydrolysis
54
ACYL CHLORIDE -> ESTER
Alcohol
55
ACYL CHLORIDE -> PRIMARY AMIDE
NH3
56
ACYL CHLORIDE -> PRIMARY AMIDE reaction
Nucleophilic addition elimination
57
ACYL CHLORIDE -> SECONDARY AMIDE
Primary amine
58
ACYL CHLORIDE -> SECONDARY AMIDE reaction
Nucleophilic addition elimination

A-Level Chemistry (42 decks)

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