Fuels for the Body: Macronutrients Flashcards
What are the three main macronutrients?
Carbohydrates, lipids and proteins.
What are the three classifications of carbohydrates?
3 classifications of carbohydrates:
- Monosaccharides- basic unit of carbs- MONOMER
- Disaccharides- 2-10 monosaccharides bonded chemically
- Polysaccharides- greater than 10 and up to thousands of sugar molecule linkages
What are the two main monosaccharide structures and what are examples?
Monosaccharides- simple sugars that contain between 3 to 7 carbons
- Pentoses- ex: Deoxyribose (DNA) and RIBOSE (RNA) , fructose (fruits)
- Hexoses- Glucose (main blood sugar) galactose (milk sugar component)
Explain how monomers of carbohydrates are joined and describe an example of processes that occur.
Monomers usually joined by DEHYDRATION SYNTHESIS reaction (hydrogen atom is removed from one monomer and hydroxide group is removed from other monomer to form water)
Ex: Oh from glucose and H from fructose removed to form water and make Sucrose
sucrose can also undergo hydrolysis- break sucrose linkage using water to create products glucose, and fructose separately.
Explain how disaccharides are formed and provide examples.
Disaccharides- simple sugar formed from 2 monosaccharides by dehydration synthesis.
-reversible reaction by hydrolysis
ex disaccharides: are SUCROSE (fructose + glucose-> table sugar), through dehydration; LACTOSE (galactose + glucose-> milk sugar); MALTOSE (glucose + Glucose; breakdown of starches
How are polysaccharides formed? What are their characteristics? provide examples.
Polysaccharides- 10 to 100s of monosaccharides joined by dehydration synthesis reactions
Usually INSOLUBLE in Water and Does NOT taste sweet
examples: Glycogen, starch, cellulose
What are the three most common polysaccharides? Differentiate between them
Polysaccharides:
1. Glycogen- MOST COMMON polysaccharide in the body, made entirely of glucose monomers
-small amount stored in liver and skeletal muscles; glycogen is BRANCHED
2. Starch- formed from glucose in PLANTS-
MAJOR carbohydrates in our diet
-long LINEAR chain of glucose monomers oriented in SAME direction
3. Cellulose- formed by PLANTS from glucose monomers
-part of CELL WALL
- long LINEAR chain of glucose monomers oriented in OPPOSITE directions.
Which of the polysaccharides are the stored forms of energy? Which one cannot be digested by humans?
GLYCOGEN and STARCH are STORED forms of energy
Cellulose CANNOT be digested by humans
Elaborate on the structure of glycogen and where it is stored. What also stores glycogen?
Glycogen- HIGHLY BRANCHED, the branches occurring every 8-10 glucose units along the backbone
-glycogen is stored mainly in LIVER (as a source of glucose) and MUSCLE tissues (as FUEL source for muscle contraction)
BACTERIA also stores glycogen as glucose reserve
glycogen has alpha 1, 4 bonds and alpha 1,6 bonds
Describe the structure of starch and the different types and where it is stored. What is the structure of Amylopectin?
Starch- glucose reserve commonly found in PLANT tissue
- it occurs as both UNBRANCHED AMYLOSE (10-30%) and BRANCHED AMYLOPECTIN (70-90%)
Amylopectin has alpha (1–> 6) branches once every 12-25 glucose units, and longer side chains than glycogen.
starch is stored as starch grains within the PLASTIDS (major organelles in plants and algae)
Compare and contrast functions of chloroplasts and amyloplasts.
Chloroplasts- sites of Carbon FIXATION an Sugar Synthesis in Photosynthesis (water and CO2 react with chlorophyll from plants and energy from sun–> glucose)
Amyloplasts- specialized for STARCH STORAGE
Explain what kind of polysaccharides fruits, leaves/wood/bark, and grains, vegetables are source of.
Leaves, wood, bark- source of cellulose, hemicellulose
fruits- source of sugar, starch, cellulose
grains-source of starch and cellulose
Vegetables- source of starch and cellulose
Explain what glycemic index is and what values indicate a low vs medium or high Glycemic index (what is good vs bad)
Glycemic index- indicates how FAST your body converts Carbs in a food into glucose
-The SMALLER the number, the LESS impact the food has on your Blood sugar
Glycemic index values:
55 or less= low (good)
56-69= Medium
70 or higher= High (bad)
potato chips= green peas < oatmeal
What is glycemic Load? What is Net Carbs?
Glycemic Load= Glycemic index/100 x Net Carbs
Net Carbs are = Total Carbohydrates - Minus Dietary Fiber
What is the well known structural polysaccharide? What is its structure and characteristics? How do they apply to mammals?
The best known structural polysaccharide- CELLULOSE found in plant cell walls
Cellulose, composed of repeating monomers of Beta-D glucose, is very ABUNDANT in PLANTS
Mammals CANNOT digest cellulose (Some mammals have microorganisms in their digestive systems that can)
Describe the role of soluble fibers and provide examples that are seen in food.
Soluble fibers- attract water and form a gel, which SLOWS digestion
-REDUCES Cholesterol and Keeps Blood sugar level
-delay emptying of your stomach and makes you feel FULL, which helps control weight
-slower stomach emptying may also affect blood sugar levels and have beneficial effect on insulin sensitivity, which may help control diabetes
-Soluble fibers also help lower LDL (bad) blood cholesterol by interfering with absorption of dietary cholesterol
Sources of soluble fiber: Oatmeal, oat cereal, lentils, apples, oranges, pears, oat bran, strawberries, nuts, flaxseeds, beans, celery, carrots, blueberries, cucumbers, dried peas.
Describe the role and characteristics of insoluble fibers. provide examples seen in food.
Insoluble Fibers- considered gut-healthy fiber since they have laxative effect and add bulk to diet, helping prevent constipation
INCREASES Bulk, PREVENTS Constipation
-These fibers do NOT dissolve in water, so they pass through gastrointestinal tract relatively intact, and speed up passage of food and waste through gut
-insoluble fibers mainly found in WHOLE grains, and Vegetables
Sources of Insoluble fibers: whole wheat, whole grains, wheat bran, corn bran, seeds, nuts, barley, couscous, brown rice, tomatoes, carrots, green beans, zucchini, broccoli, cabbage, onions, grapes, raisins, dark leafy vegetables.
What are the most common sources of fiber?
Most common sources of fiber:
- Beans
- Whole grains
- Brown rice
- Popcorn
- Nuts
- Baked potato with SKINS
- Berries
- Bran cereal
- Oatmeal
- Vegetables
What is the daily recommended intake of fiber for men and women under 50 vs over 50? what is ratio of water soluble vs insoluble fiber?
Daily Recommended intake of Fiber: -Under 50 -38 g for men -25 g for women Over 50 -30g for men -21g for women Ratio of 3:1 for water-insoluble to soluble fiber
What is the daily recommendation of carbohydrates sedentary vs physically active and athletes?
Daily recommendation of Carbohydrates: Sedentary (70kg/154 1lb person) -300 g or 40-50% total calories Physically active person -400-600g or 60% of total calories -Athlete -70% of total calories (8-10 g per kg of body mass)
Describe the various roles of carbohydrates
Role of carbohydrates
- Energy source: energy is derive from breakdown of blood-borne glucose
- Muscle glycogen powers various forms of biologic work including muscle contraction - Protein sparer: Adequate carbohydrate intake helps to preserve tissue protein
- Metabolic primer: the depletion of glycogen causes fat mobilization to exceed fat oxidation, which can lead to ketosis
- Fuel for central nervous system
- brain is almost exclusively uses blood glucose as its fuel source
- Hypoglycemia- the reduction of blood glucose to <45 mg/dL
What is hypoglycemia?
Hypoglycemia- reduction of blood glucose to less than 45 mg/dL.
Describe the carbohydrate dynamics that occurs in exercise, during high intensity, and moderate intensity.
INTENSITY and DURATION determines the fuel mixture during exercise
-high-intensity exercise
-One hour of high-intensity exercise decreases liver GLYCOGEN by 55%
-2 hours almost DEPLETES Liver and muscle glycogen
Moderate and Prolonged exercise:
-During low-intensity exercise, FAT serves as main energy substrate
What occurs during fatigue?
Fatigue- occurs when exercise continues to a point that COMPROMISES liver and muscle glycogen
commonly referred to as “HTTING THE WALL”
What synthesizes lipids? What are the three main groups of lipids?
Lipids are synthesized by PLANTS and ANIMALS 3 groups of lipids 1. simple lipids 2. Compound 3. Derived
What do simple lipids comprise of? What are the properties of Triacylglycerols (TAGs)
Simple lipids consist primarily of Triacylglycerols (TAG)
- major storage form of fat in adipocytes
- contain only one glycerol and three fatty acid chains
- the longer the fatty acid chain, the LESS water-soluble the molecule
Differentiate between Saturated fatty acids and Unsaturated fatty acids. What is an essential fatty acid?
Saturate fatty acids:
-when the carbon binds to the maximum number of hydrogens
-occurs primarily in animal products
ex: Beef, lamb, pork and egg yolk
Unsaturated fatty acids: have one or more double covalent bonds in hydrocarbon chain
-Monounsaturated- contains 1 double bond
-Polyunsaturated- contains 2 or more double bonds
-Linolenic acid is an ESSENTIAL fatty acid
What is a common example of saturated an monounsaturated fatty acid?
Saturated fatty acid - PALMITIC ACID (15 carbons; C15H31COOH)
Monounsaturated fatty acid- OLEIC acid (17 carbons; C17H33COOH)- has a kink (double bond, bent shape)
Describe what occurs in TAG (triacylglycerol) Formation and TAG Catabolism
TAG Formation: 1 glycerol and 3 fatty acids combine to form Triacylglycerol molecule and 3 water molecules are formed
glycerol-3 phosphate combines with fatty acyl using enzyme fatty acyl transferase to convert fatty acyl coa and into FAs (3 times). phosphatase also used convert phosphatidic acid into 1, 2 diacylglycerol.
TAG Catabolism- Fatty acid break down occurs as TAG molecule uses water to break down the molecule 1 by one until you end up with 1 glycerol and 1 fatty acid
Describe the composition of fatty acids in butter and coconut oil
Butter fat- has 66% of saturated FA’s, 4% of polyunsaturated FA’s and 30% of FA’s
Coconut oil: composed of 92% of saturated FA’s, 2% polyunsaturated FA’s and 6% of FA’s
Describe the different forms of compound lipids an their roles
Compound lipids:
- Phospholipids have 4 main functions:
- interact with water and lipid to modulate fluid movement across cell membranes
- maintain structural integrity of cell
- play important role in blood clotting
- provide structural integrity to Insulating sheath that surround nerve fibers - Glycolipids
- Lipoproteins
What are the four types of lipoproteins and their roles?
Four types of lipoproteins:
- Chylomicrons- TRANSPORT Vitamins A, D, E and K
- High-density Lipoprotein- (HDL) “GOOD” Cholesterol
- Very low-density lipoprotein (VLDL)- Transport TAGs to Muscle and Adipose
- Low-density lipoprotein (LDL)- “bad” Cholesterol
What are the derived lipids and their roles?
Derived lipids:
- CHOLESTEROL
- exists only in Animal tissue
- Diets high in cholesterol can cause increased risk of coronary heart disease and atherosclerosis.
What are the health concerns for Trans Fatty acids?
Trans Fatty Acids:
Health concerns:
-Increases amount of Low-density lipoprotein cholesterol (LDL)
-Decreases amount of beneficial high-density lipoprotein cholesterol (HDL)
What is the daily recommended intake for lipids?
Daily Recommended Lipid Intake:
a diet that contains 20% of total calories from lipids
-replace high fat foods with fruits, vegetables, whole grains, fish, poultry, and lean meat