Formulae, Equations & Calculations Flashcards

1
Q

How are atomic masses defined?

A

In terms of a standard atom - the unified atomic mass unit
Mass of a single atom is too small to weigh directly

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2
Q

What is the unified atomic mass?

A

One-twelfth of the mass of a carbon-12 isotope

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3
Q

What is the symbol for unified atomic mass?

A

u

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4
Q

What is the relative atomic mass (Ar) of an element?

A

The average mass of an atom of an element on a scale in which the mass of a carbon-12 atom is 12

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5
Q

How is relative atomic mass calculated?

A

Average mass of an atom divided by one twelfth of the mass of one carbon-12 atom

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6
Q

What is relative isotopic mass?

A

The mass of an atom of an isotope on a scale in which the mass of a carbon-12 atom is 12

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7
Q

What are isotopes?

A

Atoms of the same element with a different number of neutrons

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8
Q

How is average relative atomic mass calculated from isotopes?

A

Atomic mass and percentage abundance multiplied for each isotope
Total is divided by 100

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9
Q

What is relative molecular mass (Mr)?

A

The average mass of a molecule of a molecular compound on a scale in which the mass of a carbon-12 atom is 12

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10
Q

How is Mr calculated?

A

Weighted average mass of molecules is divided by one twelfth of carbon-12 atom

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11
Q

How can Mr be found from Ar?

A

By adding the relative atomic masses (Ar) of all atoms present in molecule

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12
Q

What is molecular formula?

A

Shows the number and type of each atom in molecule

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13
Q

What is empirical formula?

A

Simplest whole number ratio of elements present in one molecule of a compound

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14
Q

What is used to calculate empirical formula?

A

The ratio of masses of each element in compound

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15
Q

How is empirical formula calculated?

A

Calculate the number of moles of each element
Divide the moles of each element by the small number of moles calculated
Convert to whole number ratio

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16
Q

How is molecular formula found?

A

Divide the relative formula mass of molecular formula by relative formula mass of empirical
Multiply number of each element present in empirical formula by this number

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17
Q

What do the roman numerals represent for transition elements?

A

The charge or oxidation state as it may vary

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18
Q

What is the formulae for Silver (I)?

A

Ag⁺

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19
Q

What is the formulae for Ammonium?

A

NH₄⁺

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20
Q

What is the formulae for Zinc (II)?

A

Zn²⁺

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21
Q

What is the formulae for Hydroxide?

A

OH⁻

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22
Q

What is the formulae for Nitrate?

23
Q

What is the formulae for Sulfate?

A

SO₄²⁻

24
Q

What is the formulae for Carbonate?

A

CO₃²⁻

25
What is the formulae for Hydrogen Carbonate?
HCO₃-
26
What is the formulae for Phosphate?
PO₄³⁻
27
What is a symbol equation?
Shorthand used to describe a chemical reaction using chemical symbols to show number and type of each atom in reactants and products
28
What is a word equation?
Longer way of describing a chemical reaction using only words to show reactants and products
29
Name the rules of balancing equations.
Don't change formulae Put numbers used to balance in front of formulae In combustion reactions, balance C then H then O
30
Describe how to balance an equation.
Write formulae of reactants and products Count number of atoms in each reactant and product Balance the atoms one at a time until all are balanced Use appropriate state symbols in equation
31
What is the purpose of state symbols?
To specify the physical state of reactants and products
32
What are the four state symbols?
(s) solid (l) liquid (g) gas (aq) aqueous
33
What happens to ionic compounds in aqueous solutions?
Dissociate into ions
34
What are spectator ions?
The ions in solution that do not take part in chemical reaction
35
What is an ionic equation?
Shows only ions and particles taking part in reaction, not spectator ions
36
What factors mean not all reactants react to form products in a reaction?
Other reactions taking place simultaneously Reaction does not go to completion Reactants or products lost to atmosphere
37
What is percentage yield?
Shows how much of a particular product is formed from reactants compared to theoretical
38
How is percentage yield calculated?
Actual yield divided by theoretical yield
39
What is meant by actual yield?
Number of moles or mass of product obtained experimentally
40
What is meant by predicted yield?
Number of moles or mass of product obtained by calculation
41
How is predicted yield calculated?
Mass of substance divided by molar mass
42
What is the limiting reagent?
Reactant not in excess
43
How can the limiting reagent be determined?
Number of moles of each reactant calculated Ratio of reactants accounted for
44
What is atom economy?
Shows how many atoms used in reaction become desired product
45
How is atom economy calculated?
Molecular mass of desired product divided by sum of molecular masses of all reactants Multiply by 100
46
What atom economy do addition reactions have?
Always 100%
47
What atom economy do reactions with one product have?
Always 100%
48
What does a high atom economy mean?
Efficient and sustainable Uses fewer resources Creates less waste
49
What is water of crystallisation?
When some compounds can form crystals which have water as part of their structure
50
What is a hydrated compound?
A compound that contains water of crystallisation
51
How is water of crystallisation represented in formula?
Separated from main formula by a dot
52
What is an anhydrous compound?
A compound which doesn't contain water of crystallisation
53
What is the degree of hydration?
The amount of water molecules a substance is hydrated by
54
How can degree of hydration be calculated?
Measure mass of hydrated salt Heat salt until constant mass Difference in mass and constant mass can be used to calculate moles