Oxidation, Reduction & Redox Equations Flashcards
What is oxidation?
Addition of oxygen
Loss of hydrogen
Loss of electrons
What is reduction?
Loss of oxygen
Addition of hydrogen
Gain of electrons
What is the oxidation state of an atom?
The charge that would exist on an individual atom if bonds were fully ionic
What are oxidation states used for?
Telling if oxidation/reduction has taken place
Work out what has been oxidised and/or reduced
Construct half equations and balance redox equations
What are the oxidation states of atoms?
Neutral already, no need to add any electrons
What are the oxidation states of cations?
Need 1 electron added to become neutral
What are the oxidation states of anions?
Need 1 electron removed to become neutral
What is an oxidising agent?
A substance that oxidies another atom or ion by causing it to lose electrons
What happens to the oxidising agent itself?
It gets reduced - gaining electrons
Oxidation state decreases
What is a reducing agent?
A substance that reduces another atom or ion by causing it to gain electrons
What happens to a reducing agent itself?
Gets oxidised - loses/donates electrons
Oxidation state increases
What must be present for a reaction to be a redox reaction?
Both an oxidising and reducing agent
What are used to show oxidation states of transition metals?
Roman numerals
Why are roman numerals used to show the oxidation states of transition metals?
Can have more than one oxidation state so used to distinguish between
What are the six rules of oxidation state?
Oxidation state of any uncombined element is zero
Many atoms or ions have fixed oxidation state in compounds
Oxidation state of an element in mono-atomic ion is always same as charge
Sum of oxidation state in compound is zero
Sum of oxidation state in ion is equal to charge
In compound or ion, more electronegative element given oxidation state
What is the oxidation state of fluorine?
-1
What is the oxidation state of oxygen?
-2
What is the oxidation state of hydrogen?
+1
When is the oxidation state of hydrogen -1?
In metal hydrides
How do you know which element has a positive oxidation state in a molecule?
The more electronegative species will have the negative value
How does electronegativity trend across a period?
Increases
How does electronegativity trend down a group?
Decreases
How can the value of an element’s oxidation state be determined?
Position on periodic table
Other elements present
Do metals have positive or negative values in compounds?
Positive