Oxidation, Reduction & Redox Equations Flashcards

1
Q

What is oxidation?

A

Addition of oxygen
Loss of hydrogen
Loss of electrons

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2
Q

What is reduction?

A

Loss of oxygen
Addition of hydrogen
Gain of electrons

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3
Q

What is the oxidation state of an atom?

A

The charge that would exist on an individual atom if bonds were fully ionic

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4
Q

What are oxidation states used for?

A

Telling if oxidation/reduction has taken place
Work out what has been oxidised and/or reduced
Construct half equations and balance redox equations

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5
Q

What are the oxidation states of atoms?

A

Neutral already, no need to add any electrons

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6
Q

What are the oxidation states of cations?

A

Need 1 electron added to become neutral

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7
Q

What are the oxidation states of anions?

A

Need 1 electron removed to become neutral

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8
Q

What is an oxidising agent?

A

A substance that oxidies another atom or ion by causing it to lose electrons

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9
Q

What happens to the oxidising agent itself?

A

It gets reduced - gaining electrons
Oxidation state decreases

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10
Q

What is a reducing agent?

A

A substance that reduces another atom or ion by causing it to gain electrons

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11
Q

What happens to a reducing agent itself?

A

Gets oxidised - loses/donates electrons
Oxidation state increases

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12
Q

What must be present for a reaction to be a redox reaction?

A

Both an oxidising and reducing agent

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13
Q

What are used to show oxidation states of transition metals?

A

Roman numerals

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14
Q

Why are roman numerals used to show the oxidation states of transition metals?

A

Can have more than one oxidation state so used to distinguish between

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15
Q

What are the six rules of oxidation state?

A

Oxidation state of any uncombined element is zero
Many atoms or ions have fixed oxidation state in compounds
Oxidation state of an element in mono-atomic ion is always same as charge
Sum of oxidation state in compound is zero
Sum of oxidation state in ion is equal to charge
In compound or ion, more electronegative element given oxidation state

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16
Q

What is the oxidation state of fluorine?

17
Q

What is the oxidation state of oxygen?

18
Q

What is the oxidation state of hydrogen?

19
Q

When is the oxidation state of hydrogen -1?

A

In metal hydrides

20
Q

How do you know which element has a positive oxidation state in a molecule?

A

The more electronegative species will have the negative value

21
Q

How does electronegativity trend across a period?

22
Q

How does electronegativity trend down a group?

23
Q

How can the value of an element’s oxidation state be determined?

A

Position on periodic table
Other elements present

24
Q

Do metals have positive or negative values in compounds?

25
Do non-metals have positive or negative values in compounds?
Mostly negative
26
Are oxidation state always whole numbers?
Yes because can't have half electrons Mathematically sometimes work out fractional
27
How is a redox equation balanced?
Write unbalanced equation and indentify atoms which change in oxidation state Deduce oxidation state changes Balance oxidation state changes Balance charges Balance atoms
28
What are redox reactions?
Reactions in which oxidation and reduction take place simultaneously
29
What is a disproportionation reaction?
A reaction in which the same species is both oxidised and reduced
30
How are disproportionation reactions balanced?
Write unbalanced equation and identify atoms that change in oxidation state Deduce oxidation state changes Balance oxidation state changes Balance charges Balance atoms