Final Exam Flashcards
Decomposition Reaction
One reactant breaks down into two or more elements.
AB –> A + B
Is the solution unsaturated, saturated, or supersaturated, if I have 30 g of Potassium Nitrate in 100 g of Water at 30 C?
Unsaturated
Quantum of Energy
Absorbed when an electron moves from its ground state to its excited state.
Period
Horizontal row on the periodic table.
What is the percent composition of oxygen in CuSO₄?
mass of CuSO₄= 63.546 + 32.065 + 4(15.999) = 159.7 grams
Mass of oxygen = 4(15.999) = 64 grams
(64/159.7) x (100%) = 40.1. %O
A compound contains 21.6 g of silver and 3.21 g of sulfur, what is the percent composition?
21.6/(21.6+3.21) = 87.1% Ag
3.21/(21.6+3.21) = 12.9%S
Fusion
Solubility Curve
Used to determine the mass of solute in 100g (100ml) of water at a given temperature.
HCl + Zn →
2HCl + Zn →ZnCl₂ + H₂ Single Replacement
What are both of the symbols for each of the following types of nuclear decay:
Alpha, Beta, Gamma
Ductile
Capable of being drawn out into a wire or thread.
Weak Acid
Weak acids are not fully ionized or dissociated.
To convert a number less than 1 to scientific notation?
the original decimal point is moved n places to the right, and the resulting number is multiplied by 10^-n.
Turning Standard Notation into Scientific Notation
If the number is greater than 1, the exponent will be positive.
If the number is less than 1, the exponent will be negative.
Scientific Notation Example
Scientific notation (exponential notation) represents very large or very small numbers as powers of ten.
Write a chemical equation from the following word equation:
Magnesium reacts with aluminum chloride to form magnesium chloride and aluminum.
3Mg + 2AlCl₃–> 3MgCl₂ + 2Al
Charge of Group 16 or 6A (O,S, Se, Te):
Charge: 2-
Convert 71,200 inches to miles.
1 ft = 12 inches
1 mile = 5280 feet
Atomic Mass Number
Also known as the Mass Number or Atomic Mass.
What do significant figures show?
Precision
Metals
To the left side of the periodic table (left of the zig zag line).
Usually, solids at room temperature.
Good conductors of heat and electricity.
High melting and boiling points.
Malleable.
Ductile.
In the equation:
4Al + 3O₂→ 2Al₂O₃,
how many moles of Al₂O₃will be produced if there are 3.75 moles of O₂?
- 75 moles O₂ x (2 moles Al₂O₃/ 3 moles O₂) =
- 50 moles Al₂O₃
Anion
Negatively charged Ions. Anions are negatively charged because they have gained an electron(s) (electrons are negative). In general, anions are nonmetals.
Charge of Group 1 or 1A (H, Li, Na, K, Rb, Cs):
Charge = 1+
Diatomic Molecules
If these elements appear by themselves in an equation, the must be in pairs with the subscript 2.
(H₂, N₂, O₂, F₂, Cl₂, Br₂, I₂)
Predict the products of and write a balanced equation from the following statement:
CuCl₂ + H₂S →
CuCl₂ + H₂S →CuS + 2HCl
Double Replacement
Violations of the Octet Rule
Be - 4
B - 6
P - 8 or 10
S - 8, 10, or 12
Xe - 8, 10, or 12
Group or Family
Vertical Column on the periodic table. Elements in the same family have similar properties.
Percent Yeild
A measure of the efficiency of a reaction carried out in the laboratory.
Gases deviate most from ideal behavior under conditions of very ______ temperature and very _______ pressure
low; high
Law of Conservation of Mass
Mass is neither created or destroyed during a chemical reaction - it is conserved.
Mass Reactants = Mass Products
In the equation:
NH₄NO₃ → N₂O + 2H₂O
How many grams of H₂O are produced if you are given 50 g of NH₄NO₃?
50 g NH₄NO₃ x (1 mole NH₄NO₃ /80.04 gNH₄NO₃) x
(2 moles H₂O / 1 mole NH₄NO₃) x (18.02 g H₂O/ 1 mol H₂O) =
22.5 g H₂O
Proton
Positively charged subatomic particle. Contained inside the nucleus. Neutrons and Protons weigh roughly the same (1 atomic mass unit).
Charge of Group15 or 5A (N, P, As):
Charge = 3-
Inversely Proportional
As the value of one variable increases, the value of the other decreases and vice-versa (e.g., pressure and volume)
Reactants
Substances being mixed in a chemical reaction. The left side of the equation.
Conductor
A material which permits the flow of energy. A material which allows the flow of charged particles is an electrical conductor. A material which allows the transfer of thermal energy is a thermal conductor or heat conductor.
Charge of Group17 or 7A (F, Cl, Br, I)
Charge: 1-
Predict the products and write a balanced equation from the following word statement:
Methane (CH₄) plus Oxygen Gas forms:
Writing Formulas for Ionic Bonds
Absolute Value Criss Cross Oxidation #’s
Mg + I₂ →
Mg + I₂ →MgI₂ Synthesis
CaCl₂ + K₂CO₃ →
CaCl₂ + K₂CO₃ →CaCO₃ + 2KCl Double Replacement
Coefficients
The large numbers in front of chemical formulas. Represent the number of molecules of the substance in the reaction.
2Cl
Directly Proportional
As the value of one variable increases, the value of the other increases and vice-versa (e.g., temperature and volume, temperature and pressure)
How much solute will not dissolve if I have 80g of Potassium Nitrate in 100g of Water at 30C?
35g Potassium Nitrate
When multiplying and dividing with Significant Figures, ___________________.
round to least number of sig figs
Rules for Significant Figures?
1) ALL non-zero numbers (1,2,3,4,5,6,7,8,9) are ALWAYS significant.
2) LEADING zeroes are NEVER significant
3) Zeroes CAPTURED between non-zero numbers are ALWAYS significant.
4) TRAILING zeroes without a decimal are NEVER significant
5) TRAILING zeroes with a decimal are ALWAYS significant.
6) When using SCIENTIFIC NOTATION all digits in front of “x 10‾³” or “E-3” are ALWAYS significant
Standard Temperature & Pressure (STP) - a shorthand method that can be used when writing word problems.
Balance the following chemical equation:
__C + __O₂ → __CO₂
1C + 1O₂ → 1CO₂
The three types of radiation and their penetration abilities:
How to PREDICT PRODUCTS of the 4 Main Types of Chemical Reactions.
If the total pressure of a two gas system is 100 torr and the partial pressure of one gas is 70 torr, what is the pressure of the other gas?
Pother = 30 torr
Negative Exponents in Scientific Notation
Negative Exponents in Scientific Notation mean you should move the decimal to the left to change the number to standard notation.
STANDARD SOLUTION
Solution of known concentration
Vapor Pressure
The pressure of the vapor resulting from evaporation of a liquid (or solid) above a sample of the liquid (or solid) in a closed container.
Ideal Gas
A gas that behaves exactly as the Kinetic Molecular Theory describes
Hydronium Ion
[H+]
Oxidation Numbers
In Order +1 +2 Break until Boron +3 +4 -4 -3 -2 -1 0 at Helium
Scientific Notation in TI-84 and class calculators
(Number) 2nd EE (Exponent)
Hint: negative button is not the minus button
Electrons
Negatively charged subatomic particles. Electrons can be found in the space around the nucleus. This area is often called the electron cloud. Electrons have NO mass.
Anions
Anions are named by adding the suffix -ide to the stem of the name of the nonmetal from which they are derived. N³⁻ = Nitride O²⁻ = Oxide F⁻ = Flouride
A balloon with a volume of 2.0 L is filled with a gas at 3 atmospheres. If the pressure is reduced to 0.5 atmospheres without a change in temperature, what would be the volume of the balloon?
Since the temperature does not change, Boyle’s law can be used. Boyle’s gas law can be expressed as:
PiVi = PfVf (i=initial and f=final)
To find the final volume, solve the equation for Vf:
Vf = PiVi/Pf
Vi = 2.0 L
Pi = 3 atm
Pf = 0.5 atm
Vf = (2.0 L)(3 atm)/(0.5 atm)
Vf = 6 L/0.5
Vf = 12 L
Answer:
The volume of the balloon will expand to 12 L.
Write a chemical equation from the following word equation:
Lithium chloride reacts with magnesium nitrate to form lithium nitrate and magnesium chloride.
2LiCl + Mg(NO₃)₂ –> 2Li(NO₃) + MgCl₂
Ionic Compound Formulas
- Metal written first Nonmetal written second 2. Use criss-cross method and subscripts to insure sum of charges = 0
Convert 89.2 inches to centimeters.
2.54 cm = 1 inch
Neutrons
Neutrally charged subatomic particle. (No charge) Contained inside the nucleus. Neutrons and Protons weigh roughly the same (1 atomic mass unit)
Roman Numerals
Above groups/families Roman Numerals represent the number of valence electrons.
When writing the name of an ionic compound which includes a transition metal a Roman Numeral is used to denote the quantity of positive charge associated with that transition metal.
Properties of Bases
Bitter and slippery
Principle Energy Level
The possible locations around an atom where electrons having specific energy values (quantum number) may be found. Divided into sublevels s, p, d, and f.
In the equation:
2Na + Cl₂→ 2NaCl
How many grams of NaCl are produced from 3.75 moles of Cl₂?
- 75 moles Cl₂ x ( 2moles NaCl/1 mole Cl₂ ) x ( 58.5g NaCl / 1 mol NaCl =
- 75 g NaCl
Solvent
The component doing the dissolving.
The component in the largest amount.
Water is the universal solvent.
If pressure is constant, the volume of a sample of gas _____________ as temperature increases.
increases
At constant pressure, the volume of a sample of gas is ___________ proportional to temperature as measured on the ____________ temperature scale
directly; Kelvin
Polyatomic Ionic Formulas
- Metal written first, Polyatomic Ion is written second 2. Use criss-cross method and subscripts to insure sum of charges = 0 3. When using a subscript for polyatomic ions: place a parentheses around the polyatomic formula, put the subscript outside of the parentheses
If the [H+] =1E-5 in a Coca-Cola what is the concentration of [OH-]? Is the solution acidic, basic, or neutral?
[H+] [OH-] = 1E-14
[OH-] = (1E-14) / ([H+])
[OH-] = (1E-14) / (1E-5)
[OH-] = 1E-9
The solution is acidic because 1E-5 is less than 1E-7.
How many moles are in 3.67 x 10²⁴ molecules of SO₂?
- 67 x 10²⁴ molecules SO₂ x (1 mole SO₂/6.02x10²³ molecules SO₂)=
- 10 moles SO₂
Diatomic Molecule
If these elements appear by themselves in an equation, the must be in pairs with the subscript 2.
What is the molarity of a solution in which 58 g of NaCl are dissolved in 1.0 L of solution?
1.0 M
Malleable
Able to be hammered or pressed permenately out of it’s original shape without breaking or cracking.
CuCl₂ + H₂S →
CuCl₂ + H₂S →CuS + 2HCl Double Replacement
Write a chemical equation from the following word equation:
Water decomposes into hydrogen gas and oxygen gas:
2H₂O → 2H₂ + O₂
Properties of Ionic Compounds
Crystalline Structure High Melting Point Rigid Strong Bond Conduct Electricity (when dissolved or melted) Good Insulators
Given the following reaction: S₈ + 4Cl₂ → 4S₂Cl₂. If there is 200g of sulfur and 100g of chlorine, what mass of disulfur dichloride will be produced?
- Perform a mass-to-mass calculation between sulfur and disulfur dichloride.
200g S₈ x (1mol S₈ / 256.5g S₈) x (4mol S₂Cl₂ / 1 mol S₈) x (135g S₂Cl₂ / 1 mol S₂Cl₂) = 421g S₂Cl₂.
- Perform a mass-to-mass calculation between chlorine and disulfur dichloride.
100g Cl₂ x (1mol Cl₂ / 70.91g Cl₂) x (4mol S₂Cl₂ / 4 mol Cl₂) x (135g S₂Cl₂ / 1 mol S₂Cl₂) = 190.4g S₂Cl₂.
The limiting reactant is chlorine (Cl₂ ) because… it produced only 190.4g S₂Cl₂.
The excess reactant is sulfur (S₈) because… it would have produced 421g S₂Cl₂.
Octet Rule
All atoms other than hydrogen and helium bond to fill their valence shell with eight electrons.
Are zeros after a decimal and before a significant digit “significant” or “not significant”?
Not Significant
Atmospheric Pressure
Pressure resulting from the collisions of atoms and molecules with objects.
Symbols used in writing chemical equations
Predict the products of and write a balanced equation from the following statement:
Mg + I₂ →
Mg + I₂ →MgI₂
Synthesis
NEUTRALIZATION REACTION
When an acid and base react in solution to form salt and water.
Ionic Bond
Metals GIVE electrons, Nonmetals TAKE electrons
Balance the following chemical equation:
__C₂H₆ + __O₂ → __CO₂ + __H₂O
2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O
Saturated
Contains as much solute as it can at that temperature.
If you add more solute it will not dissolve.
Strong Acid
Completely dissociates.
pH, pOH, [H+], [OH-] Calculation Road Map