FATTY ACIDS Flashcards

1
Q

A _________ is a naturally occurring monocarboxylic acid.

A

fatty acid

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2
Q

In terms of carbon chain length, fatty acids are characterized as long-chain fatty acids (__________), medium-chain fatty acids (_________), or short-chain fatty acids
(__________).

A

a. C12 to C26
b. C8 and C10
c. C4 and C6

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3
Q

A __________ fatty acid is a fatty acid with a
carbon chain in which all carbon–carbon
bonds are single bonds.

A

saturated

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4
Q

___________ (C16) is the precursor for variety of long-chain fatty acids such as stearic acid, palmitoleic acid, and oleic acid.

A

Palmitic acid

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5
Q

IUPAC name for palmitic acid.

A

hexadecanoic acid

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6
Q

A ______________ fatty acid is a fatty acid with a carbon chain in which one carbon–carbon double bond is present.

A

monounsaturated

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7
Q

_________ is classified as a monounsaturated omega-9 fatty acid, abbreviated with a lipid number of 18:1 cis-9, and is the most abundant natural monounsaturated fatty acid in plants and animals.

A

oleic acid

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8
Q

IUPAC name for oleic acid.

A

cis-9-octadecenoic acid

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9
Q

A ___________ fatty acid is a fatty acid with a carbon chain in which two or more
carbon–carbon double bonds are present.

A

polyunsaturated

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10
Q

An ________________ is an unsaturated fatty acid with its endmost double bond three carbon atoms away from its methyl end.

A

omega-3 fatty acid

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11
Q

18:3(Δ9,12,15)

_________ is plant-based essential omega-3 polyunsaturated fatty acids that must be obtained through the diet.

A

α-Linolenic acid

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12
Q

20:4(Δ5,8,11,14)

___________ is a polyunsaturated omega-6 fatty acid 20:4(ω-6).

A

arachidonic acid

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13
Q

18:2 (n-6) or 18:2 cis-9,12

________________ is the shortest chain n-6 fatty acid and the most common PUFA in plant oils, is a biosynthetic precursor of arachidonic acid.

A

Linoleic acid

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13
Q

20:3 (n-6)

The synthesis of the __________ (20:3n-9), also known as mead acid or 5,8,11-____________, increases only when dietary intakes of omega-3 and omega-6 fatty acids are very low. Thus mead acid is one indicator of a deficiency of essential fatty acid

A

eicosatrienoic acid
Dihomo-gamma-linolenic acid (DGLA)

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14
Q

The physical properties of fatty acids, and of lipids that contain them, are largely determined by __________ and _____________.

A

the length and degree of
unsaturation of the fatty acid carbon chain

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15
Q

Solubility _________ as carbon chain length increases.

A

decreases

16
Q

Melting points for fatty acids are strongly influenced by both ___________ and _______________.

A

a. carbon chain length
b. degree of unsaturation (number of double bonds present)

17
Q

As carbon chain length increases, melting point _____________.

A

increases

18
Q

The greater the degree of unsaturation, the ____________ the reduction in melting points.

A

greater

19
Q

The decreasing melting point associated with increasing degree of unsaturation in fatty acids is explained by ______________ between carbon chains.

A

decreased molecular
attractions

20
Q

The double bonds in unsaturated fatty acids, which generally have the cis configuration, produce
__________ in the carbon chains of these molecules.

A

“bends”

21
Q

The greater the number of double bonds, the ______ efficient the packing.

A

less