Fats, oils and Lipids Flashcards

1
Q

Difference between fats and oils?

A

Fats -solid at room temp
Oils-liquid at room temp

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2
Q

Properties of fats and oils?

A

-are hydrophobic (can’t chemically mix with water )
-organic compounds composed of C, H and O (have low O2 content)
-Have high energy content due to high amount of C and H present

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3
Q

Describe the structure of fats and oils?

A

-are triglycerides- made up of 3 fatty acids and glycerol

-have a carboxyl group at one end and a methyl group at the other end

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4
Q

What is glycerol?

A

A polyhydric alcohol containing 3 carbon atoms joined to hydroxyl group

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5
Q

Describe the difference between short, medium and long chain triglycerides?

A

short chain fatty acids are C4-8
Medium chain triglycerides are C10-C14 (are well absorbed in small intestines-useful for patients with bowel problems-helps to gain weight quickly)
Long chain triglycerides- C16-C22- includes essential fatty acids
-all triglycerides contain an even number of carbon atoms if naturally occurring in foods

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6
Q

How are triglycerides formed?

A

-Each fatty acid can form an ester bond with hydroxyl (OH) group on glycerol via a condensation reaction so 3 water molecules are formed as biproduct

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7
Q

Give 2 examples of other fatty substances?

A

-Phospholipids-also have a polar head group as well as fatty acid chains (non polar)- enables to mix with water due to polar head
-Cholesterol-found in animal sources, is transported around the body with proteins

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8
Q

What is the difference between saturated and unsaturated fats?

A

Saturated-All bonds are saturated with hydrogen- there are no double bonds present between the carbons of the fatty acid chains. -normally solid at room temp and from animal sources, can be heated to high heats and maintain structure.

Unsaturated- contains double bonds, normally liquid at room temp and from plant sources (healthier-lower cholesterol)

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9
Q

Types of unsaturated fats?

A

Monounsaturated- 1 double bond
Polyunsaturated- 2 double bonds

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10
Q

How is the omega status of an unsaturated fat determined?

A

depends on where double bond is within chain-counting back from right side wherever last double bond is within chain is the omega number

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11
Q

What are essential fatty acids?

A

Essential cannot be synthesised by body must be provided in diet eg.linoleic acid,Linolenic acid,Arachidonic acid

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12
Q

What is hydrogenation?

A

When veg oils that tend to contain a large proportion of unsaturated fatty acids are either wholly (heated to 68c) or partially hydrogenated (heated to 44c) to make solid fats, eg.margarine

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13
Q

Advantages of hydrogenation?

A

-A liquid oil is changed to a semi-solid or solid because the melting point of an unsaturated fat more becomes more like that of a saturated fat.(is increased)
-The rate of oxidation decreases (stability increases with increasing saturation)
-Increases hardness and plasticity .

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14
Q

disadvantages of hydrogenation

A

-Monounsaturated and polyunsaturated fats are healthier for the heart than saturated fats
-Trans fatty acids can form which are hard to metabolize, accumulate in fatty tissue, are difficult to excrete from the body,
-Increase levels of LDL (bad) cholesterol and are a low-quality energy source

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15
Q

What are the nutritional functions of fat?

A

-rich source of energy (1g provides 9kcal)
-act as insulating layer under skin
-protect vital internal organs
-act as a carrier for fat soluble vitamins A, D, E and K.
-prevent hair and skin becoming too dry,

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16
Q

Effects of eating a diet high in saturated fats?

A

-means the body will decrease the amount of cholesterol it produces.
-it increases the amount of cholesterol in the bloodstream/arteries which can be linked to heart disease and stroke.(raise LDL cholesterol)

17
Q

Animal sources of fat?

A

Meat - visible and invisible fat
Fish - fatty fish, fish liver oils
Dairy foods - butter cream cheese

18
Q

Plant sources of fat?

A

Fruits and vegetables - avocado, olives
Nuts - brazil, walnuts,
Seeds - sesame, sunflower
Other - palm, coconut

19
Q

Difference between cis and trans fats?

A

Cis fatty acids- hydrogen bonds on same side- naturally occurring
Trans fatty acids- hydrogen bonds on opposite sides- manufactured, more unhealthy

20
Q

What is rancidity?

A

the deterioration of fats and oils leading to unpleasant odours and flavours

21
Q

How can rancidity occur?

A

-Can occur via 2 ways- hydrolytic or oxidative
-Hydrolyitic- affects dairy foods and caused by the enzyme lipase
-Oxidative- caused by contact with light, heat, oxygen or metals