Fats, oils and Lipids Flashcards
Difference between fats and oils?
Fats -solid at room temp
Oils-liquid at room temp
Properties of fats and oils?
-are hydrophobic (can’t chemically mix with water )
-organic compounds composed of C, H and O (have low O2 content)
-Have high energy content due to high amount of C and H present
Describe the structure of fats and oils?
-are triglycerides- made up of 3 fatty acids and glycerol
-have a carboxyl group at one end and a methyl group at the other end
What is glycerol?
A polyhydric alcohol containing 3 carbon atoms joined to hydroxyl group
Describe the difference between short, medium and long chain triglycerides?
short chain fatty acids are C4-8
Medium chain triglycerides are C10-C14 (are well absorbed in small intestines-useful for patients with bowel problems-helps to gain weight quickly)
Long chain triglycerides- C16-C22- includes essential fatty acids
-all triglycerides contain an even number of carbon atoms if naturally occurring in foods
How are triglycerides formed?
-Each fatty acid can form an ester bond with hydroxyl (OH) group on glycerol via a condensation reaction so 3 water molecules are formed as biproduct
Give 2 examples of other fatty substances?
-Phospholipids-also have a polar head group as well as fatty acid chains (non polar)- enables to mix with water due to polar head
-Cholesterol-found in animal sources, is transported around the body with proteins
What is the difference between saturated and unsaturated fats?
Saturated-All bonds are saturated with hydrogen- there are no double bonds present between the carbons of the fatty acid chains. -normally solid at room temp and from animal sources, can be heated to high heats and maintain structure.
Unsaturated- contains double bonds, normally liquid at room temp and from plant sources (healthier-lower cholesterol)
Types of unsaturated fats?
Monounsaturated- 1 double bond
Polyunsaturated- 2 double bonds
How is the omega status of an unsaturated fat determined?
depends on where double bond is within chain-counting back from right side wherever last double bond is within chain is the omega number
What are essential fatty acids?
Essential cannot be synthesised by body must be provided in diet eg.linoleic acid,Linolenic acid,Arachidonic acid
What is hydrogenation?
When veg oils that tend to contain a large proportion of unsaturated fatty acids are either wholly (heated to 68c) or partially hydrogenated (heated to 44c) to make solid fats, eg.margarine
Advantages of hydrogenation?
-A liquid oil is changed to a semi-solid or solid because the melting point of an unsaturated fat more becomes more like that of a saturated fat.(is increased)
-The rate of oxidation decreases (stability increases with increasing saturation)
-Increases hardness and plasticity .
disadvantages of hydrogenation
-Monounsaturated and polyunsaturated fats are healthier for the heart than saturated fats
-Trans fatty acids can form which are hard to metabolize, accumulate in fatty tissue, are difficult to excrete from the body,
-Increase levels of LDL (bad) cholesterol and are a low-quality energy source
What are the nutritional functions of fat?
-rich source of energy (1g provides 9kcal)
-act as insulating layer under skin
-protect vital internal organs
-act as a carrier for fat soluble vitamins A, D, E and K.
-prevent hair and skin becoming too dry,