Exam 3 Review Flashcards

1
Q

What is the formula for wavelength?

A

λ = c / f

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2
Q

What is c?

A

c is the speed of light (approximately 3.00 x 10^8 m/s)

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3
Q

What is f?

A

f is the frequency in Hertz (Hz)

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4
Q

How do you convert m to nm?

A

1 m x 10^9 nm

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5
Q

How do you calculate energy of a photon?

A

E = hc/λ

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6
Q

What is h?

A

Planck’s constant.

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7
Q

What is Planck’s constant?

A

6.626 × 10^-34 J·s

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8
Q

What is c?

A

3.00x10^8

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9
Q

What is the Rhydberg equation?

A

ΔE = -RH (1/nf^2 - 1/ni^2)

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10
Q

What is RH?

A

RH = 2.179 × 10 ^ -18 J

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11
Q

What is l for s orbitals?

A

0

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12
Q

What is l for p orbitals?

A

1

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13
Q

What is l for d orbitals?

A

2

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14
Q

What is l for f orbitals?

A

3

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15
Q

When does effective nuclear charge increase?

A

Effective nuclear charge increases across a row due to increasing number of protons.

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16
Q

When does electron shielding occur?

A

Electron shielding occurs when inner energy levels disrupt attractive forces between the nucleus and the electrons in the outer energy level.

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17
Q

What is atomic radius?

A

The size of the atom.

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18
Q

When does atomic radius decrease?

A

It decreases across a row left to right due to increased nuclear charge pulling valence electrons in outer energy level closer to the nucleus.

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19
Q

When does atomic radius increase?

A

Radius increases down a row due to increased shielding, reducing attraction of valence electrons to nucleus and making atom larger.

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20
Q

What is ionization energy?

A

Ionization energy is energy required to remove an electron from an atom.

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21
Q

When does ionization energy decrease?

A

It decreases down a row due to electron shielding.

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22
Q

When does ionization energy increase?

A

It increases going across a row due to increased nuclear charge.

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23
Q

What is electron affinity?

A

Electron affinity is energy released when an atom adds an electron.

24
Q

When does electron affinity increase?

A

It increases going across a row.

25
When does electron affinity decrease?
It decreases going down a column.
26
Which bonds are sigma bonds?
The first bond.
27
What are pi bonds?
The following bonds.
28
What is the bond order?
Total number of bonds.
29
How to find valence electrons?
Count how many over the element is. If there is a positive charge, deduct that number of electrons. If there is a negative charge, add that number of electrons.
30
What makes bond energy high?
More bonds.
31
What makes bond energy low?
Less bonds.
32
What makes bond length high?
Less bonds.
33
What makes bond length low?
More bonds.
34
What are the electron domains?
The total number of bonding pairs and lone pairs in a molecule.
35
How to find hybridization?
It’s always dependent on the number of electron domains.
36
What does it mean when the electron pair geometry is linear?
There are 2 domains.
37
What does it mean when the electron pair geometry is trigonal planar?
There are 3 domains.
38
What does it mean when the electron pair geometry is tetrahedral?
There are 4 domains.
39
What does it mean when the electron pair geometry is trigonal bipyramidal?
There are 5 domains.
40
What does it mean when the electron pair geometry is octahedral?
There are 6 domains.
41
What does it mean when molecular geometry is linear?
There are 2 bonding pairs.
42
What does it mean when molecular geometry is trigonal planar?
There are 3 bonding pairs.
43
What does it mean when molecular geometry is bent?
There are 2 bonding pairs and 1 lone pair or 2 bonding pairs and 2 lone pairs.
44
What does it mean when molecular geometry is trigonal pyramidal?
There are 3 bonding pairs and 1 lone pair.
45
What does it mean when 5 domain molecular geometry is see saw?
There are 5 bonding pairs.
46
What does it mean when 5 domain molecular geometry is t-shaped?
There are 3 bonding pairs and 2 lone pairs.
47
What does it mean when 5 domain molecular geometry is linear?
There are 2 bonding pairs and 3 lone pairs.
48
What does it mean when 6 domain molecular geometry is octahedral?
There are 6 bonding pairs.
49
What does it mean when 6 domain molecular geometry is square pyramidal?
There are 5 bonding pairs and 1 lone pair.
50
What does it mean when 6 domain molecular geometry is square planar?
There are 4 bonding pairs and 2 lone pairs.
51
What are dispersion forces?
A nonpolar particle can be temporarily polarized to create dispersion force.
52
What are dipole-dipole interactions?
Polar molecules have a more positive and a more negative end—a dipole. The oppositely charged ends attract each other.
53
What are hydrogen bonds?
A hydrogen bond is an attraction between a hydrogen atom attached to a highly electronegative atom and a nearby small electronegative atom in another molecule or chemical group.
54
What elements can form a hydrogen bond?
Hydrogen bonding arises in part from the high electronegativity of nitrogen, oxygen, and fluorine.
55
What does it mean for a molecule to be polar?
It’s bond dipoles are not symmetrical.
56
What does it mean for a molecule to be nonpolar?
The bond dipoles cancel, i.e., equal and/or arranged symmetrically around the center.