Exam 3 Flashcards
Soil pH impact on growth and functioning of soil organisms
-greatly influences root uptake availability of nutrients
-influences activity of microorganisms and type of vegetation
-affects mobility of pollutants in soil
-controls chemistry of soils and waters
Hydrogen ions
cause acidity
combination pH electrode
measuring soil pH with H+ selective glass electrode
how do soils become acid
addition of H+ ions from acid-forming processes
exchange of 2 H+ ions for a Ca2+ ion
Anions of acids –> leaching loss of Ca, Mg, K, and Na
Production of H+
carbonic acid from CO2
organic acid dissociation
oxidation of N and S
cation uptake
cation ppt
consumption of H+
carbonate input
organic anion protonation
reduction of N, S, Fe
anion uptake
cation weathering
role of Al in soil acidity
Al3+ ions have a tendency to hydrolyze
Al3+ combines with OH- leaving the H+ to lower the pH of the soil solution
a single Al3+ ion can release up to 3 H+ ions
bufferring capacity
ability of the soil to resist change in pH as a result of reserve and exchangeable activity
factors to consider when using lime
-plant’s soil pH preference
-soil properties
-initial pH
-soil buffering capacity
-amount of soil to be treated
-nature of liming material
human influenced soil acidification
-natural processes of acidification accelerated
-nitrogen amendments
-acid precipitation
-exposure of potential acid sulfate soils
acid rain
gaseous and particulate pollutants in atmosphere –> cloud water –> rain
effects of acid rain
weathers marble and structures
vegetation damaged from the top down
acid mine drainage
exposed pyrite reacts with water and oxygen to form sulfuric acid
acid soils are prominent in
humid climates with intense weathering and leaching
basic soils are prominent in:
arid climates with a lack of weathering or leaching
alkalinizing processes that consume H+ or produce OH-
-weathering of nonacid cations from minerals
-accumulation of nonacid cations
-production of base-producing anions
-excess anion uptake by roots
causes of soil salinity
-rainfall
-irrigation with poor drainage
-capillary rise followed by evaporation
-landforms
-de-icing salt
-salt water intrusion
major salts in soil salinity
cations
-sodium
-calcium
-magnesium
anions
-chloride
-sulfate
-bicarbonate
-carbonate
-nitrate
salt-affected soil impacts on plants
-toxicity of: sodium, boron, chloride, bicarbonate
-cation imbalance
-soil dispersion by sodium
-water stress
salinity
high total dissolved salts
sodicity
high exchangeable sodium
what makes (saline) sodic soil alkaline
-salts split water molecules into H+ or OH-
-carbonates
-bicarbonates
-carbonate and bicarbonate react with water to release hydroxyls
-solubility at high pH
soil organisms major flows
energy, mineral nutrients, carbon
macrofauna
> 2 mm
earthworms, gophers, cicadas, ants