Exam 1 Session 2 Flashcards

0
Q

The point In the curve at which the acid is exactly neutralized is called the ______.

A

Inflection point or equivalence point

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1
Q

A titration is an experiment in which measured amounts of ___ are added to a measured amount of ___.

A

Base (salt) and Acid

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2
Q

The +/- 1 rule defines the ____ region of a solution.

A

Buffer

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3
Q

A buffer solution consist of a ___ acid and it’s conjugate base.

A

Weak

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4
Q

The +/- 2 rule defines the ______ region of a solution.

A

All or nothing

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5
Q

2 ph units above a functional groups pKa, it will be fully _____.

A

Deprotonated

COO- or NH2

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6
Q

2 ph units below a functional groups pKa, it will be fully ______.

A

Protonated

COOH or NH3 +

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7
Q

The general structure of an amino acid includes a/n ______ group a/n ____ group, an R group, and a H group, all bound to a central alpha carbon.

A

Amino, carboxyl

R group = side chain

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8
Q

The _____ determines the identity of the particular amino acid.

A

R group

Identity means polar, nonpolar, etc..

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9
Q

Glycine alanine and leucine are examples of ____ amino acids.

A

Non polar

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10
Q

Contain no _____ atoms in their side chains so they will not readily hydrogen bond.

A

Electronegative

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11
Q

They may have van der waals forces or hydrophobic interactions.

A

Glycine, leucine, alanine

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12
Q

Serine, tyrosine, and cysteine are examples of ____ amino acids.

A

Neutral polar

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13
Q

Aspartate, glutamate, and lysine are examples of ______ amino acids.

A

Charged polar

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14
Q

In a free amino acid the carboxyl group and the amino group of the general structure are charged at neutral ph. A ______ has equal positive and negative charges. In solution it is electrically neutral.

A

Zwitterion

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15
Q

The ph at which a molecule has no net charge is called the _______.

A

Isoelectric point

16
Q

The symbol for isoelectric point is____.

A

PI

17
Q

For nonpolar and most neutral polar side chains the average isoelectric point value is ____.

A

6

pKa of the carboxyl group decreases the pKa of the amino group.

18
Q

For cystine the average isoelectric point value is _____.

A

5

The pKa of the carboxyl group decreases the pKa of the side chain.

19
Q

For histidine the average isoelectric point value is _____.

A

7.6 the pKa of the side side chain amino group and the pKa of the side chain.