Exam 1 Flashcards

1
Q

According to the de broglie equation, if two objects are moving at the same speed…

A

Doubling the mass of one of the objects will have the same effect on its wavelength as does doubling the speed

If one object has twice as much mass as the other, it’s wavelength is one-half the wavelength of the other

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2
Q

De broglie equation

A

Relates the wavelength of any moving company beefy to its mass and it’s speed

Wavelength=h/mu

H-plank constant

M-mass

U-velocity

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3
Q

Orbitals with larger values of n are….

A

Shells that are greater distance from the nucleus and have higher energies than those with lower values of n

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4
Q

Value of L and letter identifier

A
S-0
P-1
D-2
F-3
G-4

(These can be positive or negative numbers and go through interferes in between them- Ex if L=4 then ml can be -3, -2, -1, 0, 1, 2, 3)

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5
Q

Magnetic quantum number (ml)

A

Defines the orientation of an orbital in space. An internet that may have any value from -l to +l, where l is the angular momentum quantum number

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6
Q

Heisenberg uncertainty principle

A

The principle that one cannot simultaneously know the exact position and the fact momentum of an electron

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7
Q

As quantum number n increases, the size of the orbital….

A

Also increases

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8
Q

Wavelength of light from lowest energy to highest energy

435nm
565nm
673nm

A

Lower numbers have higher energy

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9
Q

Characteristics that apply to an atomic orbital

A

Identified by a unique combination of THREE quantum numbers

A region around the nucleus of an atom where the probability of finding an electron is high

Defined by the square of the wave function

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10
Q

Degenerate orbitals

A

Need to be of the same energy

They Don’t have to be of same shape or even angular momentum quantum numbers

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11
Q

Aubau principle

A

The concept of building up ground state atoms so that their electrons occupy the lowest energy orbitals available

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12
Q

How to find how many moles of a specific atom are in a compound

A

Multiple it’s subscript with the number of moles in compound

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13
Q

Relationship between frequency and wavelength

A

They are inversely proportional λν=c

Same with energy and wavelength

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14
Q

Excited state atom

A

total energy of the electrons can be lowered by transferring one or more electrons to different orbitals. That is, in an excited-state atom not all electrons are in the lowest possible energy levels.

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15
Q

Hunds rule

A

Every orbital is singly occupied before it is doubly occupied

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16
Q

Ground state

A

Lowest energy electron configuration for that atom

17
Q

Excited state

A

An electron can transition from a lower state to a higher energy level by absorbing a quantity of energy (ΔE) that exactly matches the energy difference between two states

This process is called absorption

18
Q

Excited state is more or less stable…why

A

Less stable

Electron from a higher energy level will then transition to a lower energy level

19
Q

Transitions to higher states (absorption) have _____ΔE values

A

Positive

20
Q

Transitions to lower states (emission) have ______ ΔE values

A

Negative

21
Q

Represents the number of joules in a single quantum of energy

A

E

22
Q

A quantum of electromagnetic radiation

A

Photon

23
Q

Vo

A

Threshold frequency

The minimum frequency of light required to produce the photoelectric effect

24
Q

Work function

A

Minimum quantity of energy needed to emit photoelectrons from a photoelectric material

Related to strength of attraction between the nucleus of metals atom and the electrons surrounding its nuclei

25
Q

De broglie equation

A

λ=h/mu

26
Q

The more momentum a particle has…. the ____its de profile wavelength

A

Shorter

27
Q

1J=

A

1kg•m2/s2

28
Q

Aufbau principle

A

Each electron goes into the lowest energy orbital available

29
Q

Pauli exclusion principle

A

No two electrons can have the same set of four quantum numbers

30
Q

Heisenberg uncertainty principle

A

We can not determine both the position and the momentum of an electron in an atom at the same number

31
Q

Where do degenerate orbitals occur

A

P
D
F

32
Q

Hunds rule

A

The lowest energy electron configuration of an atom has the maximum number of unpaired electrons, all of which have the same spin degenerate orbitals

Also-each orbitals in a sub level is singly occupies before any orbital is doubly occupied

33
Q

One isotope makes 97% of calcium atoms..which one?

A

40Ca

34
Q

Isotopes have

A

Same atomic number but different mass number

35
Q

Pauli exclusion principle

A

no two electrons can have the same four electronic quantum numbers

36
Q

An ion is formed when

A

Electron is taken from highest energy orbital (n value)

37
Q

Anode

A

Device where current flows IN from outside

(Oxidation)

(Don’t panic) (positive is anode negative is cathode)

38
Q

Cathode

A

Decide where current flows OUT

(Reduction)

(Don’t panic) (positive is anode negative is cathode)