Ether and Epoxide Flashcards
1
Q
ether synthesis RO- –> ROCH2R, X- product
A
R-CH2X
2
Q
ether synthesis C=C –> H-C-C-OR
A
ROH, (CF3CO2)2Hg
NaBH4
3
Q
ether R-O-R –> R-X and R-OH
A
HX, H2O
4
Q
O epoxide –> 2 -OH groups
A
H3O+
5
Q
O epoxide –> -OH and -Br
A
HBr
6
Q
O epoxide –> -OH and -OR
A
RO-, ROH
7
Q
O epoxide and RMgX –> -OH and -R
A
Ether
H3O+
8
Q
thiol synthesis -Br –> -SH
A
(H2N)2C=S
H2O
9
Q
disulfide synthesis 2 R-SH –> RS-SR
A
I2, H2O
10
Q
sulfide synthesis RS- –> RSCH2R, Br- product
A
RCH2Br
11
Q
add =O to S with 2 constituents
A
H2O2
12
Q
add =O to S with 3 constituents
A
RCO3H
