Aldehyde and Ketone Flashcards
1
Q
aldehyde synthesis primary alcohol –> aldehyde
A
Dess-Martin periodinane, CH2Cl2
2
Q
ester –> aldehyde, ROH product
A
DIBAH, toluene
H3O+
3
Q
secondary alcohol –> ketone
A
Periodinane or CrO3
4
Q
ketone -Cl –> -R
A
R2CuLi
ether
5
Q
aldehyde -H –> -OH
A
CrO3, H3O+
6
Q
=O –> -H and -OH
A
NaBH4, ethanol
H3O+
7
Q
=O –> -R and -OH
A
R-MgX, ether
H3O+
8
Q
=O –> -CN and -OH
A
HCN
9
Q
=O –> -NR, H2O product
A
RNH2
10
Q
C=O –> C=C-NR2, H2O product
A
HNR2
11
Q
=O –> -H and -H, H2 product, H2O product
A
H2NNH2, KOH
12
Q
=O –> -OR and -OR, H2O product
A
2ROH, acid catalyst
13
Q
=O –> R-C=C-R, (C6H5)3P=O product
A
(C6H5)3P-CHR, THF
14
Q
C=C –> H-C-C-NHR
A
RNH2
15
Q
turn C=C –> H-C-C-OH
A
H2O
16
Q
C=C –> H-C-C-R
A
R2CuLi, ether
H3O+
