Benzene Flashcards by Lilian Liu

Q

benzene fluorination add -F

A

F-TEDA-BF4
TfOH

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Q

benzene bromination add -Br, HBr product

A

Br2, FeBr3

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Q

benzene chlorination add -Cl, HCl product

A

Cl2, FeCl3

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Q

benzene iodination add -I, HI product

A

I2, CuCl2

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Q

benzene nitration add -NO2, H2O product

A

HNO3, H2SO4

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Q

benzene sulfonation add -SO3H

A

SO3, H2SO4

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Q

Friedel-Crafts alkylation add -R, HCl product

A

R-Cl, AlCl3

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Q

Friedel-Crafts acylation add R-C=O , HCl product

A

R-C=O , AlCl3

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Q

benzene -NO2 –> -NH2

A

Fe, H3O+
HO-

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Q

benzene -Cl –> -OH, NaCl product

A

Na+, -OH, H2O (needs withdrawing group -NO2)

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Q

benzene -Br –> -NH2, NaBr product

A

Na+, -NH2, NH3

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Q

alkylbenzene -CH3 –> -CO2H

A

KMnO4, H2O

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Q

alkylbenzene bromination -CH3 –> -CH2BR

A

NBS, (PhCO2)2, CCl4

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Q

benzene –> cyclohexane

A

H2, Rh/C catalyst

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Q

reduction of aryl alkyl ketone C=O –> CH2

A

H2/Pd, ethanol

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