Equillibrium ( DEFINITIONS ) Flashcards
Endothermic Reaction
- Energy enters reaction
- Energy considered part of reactants
Exothermic
- Energy exists in the reaction
- Energy is considered part of the products
Closed System
No substance can enter or leave reaction
Open System
Matter can enter or leave reaction
Dynamic Equilibrium
Forward and Reverse reactions are occurring at the same time and rate
- Represented with double arrow
- Occurs in closed system
Steady State
A system that is unchanging at the visible and molecular level
- Occurs in Open Systems
- NOT equilibrium
Forward Reaction
- Left to Right
- Reactants to Products
Reverse Reaction
- Right to Left
- Products to Reactants
Le Chatelier’s Principle
When stress is applied to a system in dynamic equilibrium, it will shift to relieve that stress.
3 stresses:
- Concentration
- Temperature
- Pressure + Value
Spontaneity
- Reaction happens easily on its own
- Products favoured
- Large equilibrium constant (>1)
Non-Spontaneous Reactions
- Does NOT happen easily, if not at all
- Reactants favoured
- Small equilibrium constant (<1)
Solubility
Maximum amount of solute that dissolves in a quantity of solvent at a specific temperature
Solute
Substance that dissolves
Solvent
Substance that does dissolving
Soluble
Can dissolve
Insoluble
Can’t dissolve
Miscible
Liquid dissolve in Liquid
Dissociation
Separation of ions in an ionic compound
Aqueous
Water containing dissolves substances
Precipitate
Solid formed after dissolving a substance in liquid
Net Ionic Equation
Chemical equation that shows only those ions directly involved in the chemical reaction
Spectator Ion
Does not precipitate in the reaction
Saturated Solution
When as much solute as possible has been dissolved in the solvent at that temperature
Unsaturated Solution
Solvent can still dissolve more solute
Supersaturated Solution
Contains more than the maximum amount of dissolved solute at a given temperature
Solubility Product Constant (Ksp)
Equilibrium constant for a solid substance dissolving in an aqueous solution
- Represents level at which a solute dissolves in a solution
- More soluble substance = Higher Ksp value