equilibrium keywords Flashcards
bond energy/ bond enthalpy
the energy needed to break 1 mole of a particular bond in 1 mole of gaseous molecules.
enthalpy change of formation
the enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions (at 25 oC 1 atm).
sign of enthalpy change of formation
can be (+) can be (-)
enthalpy change of combustion
the enthalpy change when 1 mole of a substance is completely burned in oxygen under standard conditions (at 25°C 1 atm).
sign of enthalpy change of combustion
always (-)
enthalpy change of hydration
the enthalpy change when 1 mole of a specified gaseous ion dissolves in sufficient water to form a very dilute solution.
sign of enthalpy change of hydration
always (-)
enthalpy change of atomisation
the enthalpy change when an element or a molecule is converted into 1 mole of free gaseous atoms under standard conditions (at 25°C 1 atm).
sign of enthalpy change of atomisation
always (+)
enthalpy change of neutralisation
the enthalpy change when 1 mole of water is formed from the neutralisation between acid and alkali under standard conditions (at 25°C 1 atm).
sign of enthalpy change of neutralisation
always (-)
enthalpy change of solution
the energy absorbed or released when 1 mole of an ionic solid dissolves in sufficient water to form a very dilute solution.
sign of enthalpy change of solution
can be (+) can be (-)
Na+(g) + aqueous solution -> Na+(aq)
enthalpy change of hydration
NH4Cl(s) + aq -> NH4+(aq) + Cl-(aq)
enthalpy change of solution
Al(s) -> Al(g)
enthalpy change of atomisation
1/2 O2(g) -> O(g)
enthalpy change of atomisation
mean bond enthalpy
the energy needed in breaking (a) covalent bond(s) averaged for that type of bond over a range of molecules
reversible reaction
a reaction in which products can be changed back to reactants by reversing the conditions
dynamic equilibrium
in an equilibrium mixture, molecules of reactants are being converted into products (forward reaction) at the same rate as products are being converted to reactants (reverse reaction).
You have a reversible reaction in a state of dynamic equilibrium.
suggest why something is very insoluble in water, besides if it having strong covalent bonds. in terms of enthalpy change.
its enthalpy change of solution is very positive
standard enthalpy change of a reaction
Heat change measured at constant pressure measured at standard conditions