equilibrium keywords Flashcards

1
Q

bond energy/ bond enthalpy

A

the energy needed to break 1 mole of a particular bond in 1 mole of gaseous molecules.

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2
Q

enthalpy change of formation

A

the enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions (at 25 oC 1 atm).

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3
Q

sign of enthalpy change of formation

A

can be (+) can be (-)

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4
Q

enthalpy change of combustion

A

the enthalpy change when 1 mole of a substance is completely burned in oxygen under standard conditions (at 25°C 1 atm).

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5
Q

sign of enthalpy change of combustion

A

always (-)

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6
Q

enthalpy change of hydration

A

the enthalpy change when 1 mole of a specified gaseous ion dissolves in sufficient water to form a very dilute solution.

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7
Q

sign of enthalpy change of hydration

A

always (-)

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8
Q

enthalpy change of atomisation

A

the enthalpy change when an element or a molecule is converted into 1 mole of free gaseous atoms under standard conditions (at 25°C 1 atm).

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9
Q

sign of enthalpy change of atomisation

A

always (+)

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10
Q

enthalpy change of neutralisation

A

the enthalpy change when 1 mole of water is formed from the neutralisation between acid and alkali under standard conditions (at 25°C 1 atm).

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11
Q

sign of enthalpy change of neutralisation

A

always (-)

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12
Q

enthalpy change of solution

A

the energy absorbed or released when 1 mole of an ionic solid dissolves in sufficient water to form a very dilute solution.

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13
Q

sign of enthalpy change of solution

A

can be (+) can be (-)

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14
Q

Na+(g) + aqueous solution -> Na+(aq)

A

enthalpy change of hydration

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15
Q

NH4Cl(s) + aq -> NH4+(aq) + Cl-(aq)

A

enthalpy change of solution

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16
Q

Al(s) -> Al(g)

A

enthalpy change of atomisation

17
Q

1/2 O2(g) -> O(g)

A

enthalpy change of atomisation

18
Q

mean bond enthalpy

A

the energy needed in breaking (a) covalent bond(s) averaged for that type of bond over a range of molecules

19
Q

reversible reaction

A

a reaction in which products can be changed back to reactants by reversing the conditions

20
Q

dynamic equilibrium

A

in an equilibrium mixture, molecules of reactants are being converted into products (forward reaction) at the same rate as products are being converted to reactants (reverse reaction).

You have a reversible reaction in a state of dynamic equilibrium.

21
Q

suggest why something is very insoluble in water, besides if it having strong covalent bonds. in terms of enthalpy change.

A

its enthalpy change of solution is very positive

22
Q

standard enthalpy change of a reaction

A

Heat change measured at constant pressure measured at standard conditions