environmental chemistry Flashcards
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what are siderophiles and where can you find them
iron loving, FE NI CO In the core
lithophile elements
Elements which predominantly
bond with oxygen and are
concentrated in the mantle and the
crust
chalcophile
elements
Elements which prefer to bond with
sulfur are called
Bioremediation
Micro-organisms or microbial processes to remove/degrade contaminants from an
area. Remediation greatly helps to cleanse the water of its contaminants before it
reaches the groundwater
nitrates
Nitrite → Methemoglobinemia
eutrophication
Enrichment of water by nitrogen compounds, causing an accelerated
growth of algae and higher forms of plant life to produce an undesirable
disturbance to the balance of organisms present in the water and to the
quality of the water concerned
Dissolution
Many minerals in the Earth’s crust are soluble, Halite (NaCl), Gypsum
(CaSO4
∙2H2O), etc.
These can dissolve directly in water
Others react with naturally acidic rain water:
2 NaAlSi3O8(s) + 9 H2O(l) + 2H2CO3(aq)Al2Si2O5(OH)4(s) + 2 Na+(aq) + 2 HCO3-(aq) + 4 H4SiO4(aq)
Oxidation
Iron(II), manganese(II), and sulphur can undergo oxidative weathering
under normal atmospheric conditions
Sulphide minerals such as pyrite, FeS2
, are particularly
susceptible
Hydrolysis
Water acts as both solvent and reagent Mg2SiO4(s) + 4 H2O(l) 2 = Mg(OH)2(aq) + H4SiO4(aq
Acid hydrolysis
Acid acts as the hydrolysing agent
Mg2SiO4(s) + 4 H2CO3(aq) 2 Mg2+(aq) + 4 HCO3-(aq) + H4SiO4(aq)