enthalpy changes Flashcards

1
Q

exothermic reaction

A

heat energy is released to the surroundings (ΔH is negative)

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2
Q

endothermic reaction

A

heat energy is absorbed from the surroundings (ΔH is positive)

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3
Q

average bond enthalpy

A

average enthalpy change for the breaking of one mole of bonds in gaseous molecules

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4
Q

standard conditions

A

298K
101kPa
1.0moldm-3

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5
Q

enthalpy change of neutralisation

A

enthalpy change when one mole of water is formed by neutralisation

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6
Q

enthalpy change of formation

A

enthalpy change when one mole of a compound is formed from its elements

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7
Q

enthalpy change of combustion

A

enthalpy change when one mole of a compound undergoes complete combustion

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8
Q

hess’ law

A

the enthalpy change of a reaction depends only on the initial and final states and is independent of the route taken

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9
Q

homolytic fission

A

bond breaks evenly to form two radicals

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10
Q

heterolytic fission

A

bond breaks unevenly to form two ions

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11
Q

enthalpy change of reaction

A

ΔrH = ΔH(breaking bonds) - ΔH(forming bonds)

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12
Q

enthalpy changes when making/breaking bonds

A

mexo bendo
making bonds is exothermic
breaking bonds is endothermic

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13
Q

using ΔfH data

A

use fliPpeR
arrows upwards
products - reactants

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14
Q

using ΔcH data

A

use cRaP
arrows downwards
reactants - products

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15
Q

calculating enthalpy change of reaction from experimental data

A

q = mcΔt
ΔH = q / n

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