enthalpy changes Flashcards
exothermic reaction
heat energy is released to the surroundings (ΔH is negative)
endothermic reaction
heat energy is absorbed from the surroundings (ΔH is positive)
average bond enthalpy
average enthalpy change for the breaking of one mole of bonds in gaseous molecules
standard conditions
298K
101kPa
1.0moldm-3
enthalpy change of neutralisation
enthalpy change when one mole of water is formed by neutralisation
enthalpy change of formation
enthalpy change when one mole of a compound is formed from its elements
enthalpy change of combustion
enthalpy change when one mole of a compound undergoes complete combustion
hess’ law
the enthalpy change of a reaction depends only on the initial and final states and is independent of the route taken
homolytic fission
bond breaks evenly to form two radicals
heterolytic fission
bond breaks unevenly to form two ions
enthalpy change of reaction
ΔrH = ΔH(breaking bonds) - ΔH(forming bonds)
enthalpy changes when making/breaking bonds
mexo bendo
making bonds is exothermic
breaking bonds is endothermic
using ΔfH data
use fliPpeR
arrows upwards
products - reactants
using ΔcH data
use cRaP
arrows downwards
reactants - products
calculating enthalpy change of reaction from experimental data
q = mcΔt
ΔH = q / n