energy transfer in reactions 9/3/25 Flashcards

1
Q

What is the definition of bond energy?

A

The amount of energy required to break one mole of a bond in a molecule.

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2
Q

True or False: Energy is released when bonds are formed.

A

True

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3
Q

What is the formula for calculating the overall energy change in a reaction?

A

Overall energy change = Total bond energies of reactants - Total bond energies of products

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4
Q

Fill in the blank: The process of breaking bonds requires _____ energy.

A

input

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5
Q

What type of reaction absorbs energy from the surroundings?

A

Endothermic reaction

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6
Q

What type of reaction releases energy to the surroundings?

A

Exothermic reaction

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7
Q

What is the unit of bond energy?

A

Kilojoules per mole (kJ/mol)

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8
Q

True or False: The bond energy of a double bond is generally higher than that of a single bond.

A

True

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9
Q

What does the term ‘reaction rate’ refer to?

A

The speed at which reactants are converted into products in a chemical reaction.

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10
Q

Which factor does NOT affect the rate of a chemical reaction?

A

The color of the reactants

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11
Q

Fill in the blank: Increasing the temperature generally _____ the reaction rate.

A

increases

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12
Q

What is the effect of increasing concentration on reaction rate?

A

It typically increases the reaction rate.

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13
Q

What role do catalysts play in chemical reactions?

A

They speed up the reaction rate without being consumed.

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14
Q

True or False: A higher surface area of reactants increases the reaction rate.

A

True

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15
Q

What is a common method for measuring the rate of a reaction?

A

Measuring the change in concentration of reactants or products over time.

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16
Q

Fill in the blank: The rate of reaction can be expressed as the change in _____ over time.

A

concentration

17
Q

What does a steeper slope on a concentration vs. time graph indicate?

A

A faster reaction rate.

18
Q

What is activation energy?

A

The minimum energy required for a reaction to occur.

19
Q

True or False: All reactions require activation energy to start.

20
Q

What does the term ‘endothermic’ imply about a reaction?

A

It absorbs heat energy from the surroundings.

21
Q

What is the effect of pressure on the reaction rate of gases?

A

Increasing pressure generally increases the reaction rate.

22
Q

What is the difference between a homogeneous and heterogeneous catalyst?

A

Homogeneous catalysts are in the same phase as the reactants; heterogeneous catalysts are in a different phase.

23
Q

Fill in the blank: The energy profile of an exothermic reaction shows energy _____ during the reaction.

24
Q

What is the role of temperature in the collision theory?

A

Higher temperatures increase the energy and frequency of collisions between particles.

25
True or False: A catalyst lowers the activation energy of a reaction.
True
26
What happens to the reaction rate when temperature is decreased?
The reaction rate generally decreases.
27
What is the significance of the transition state in a chemical reaction?
It is a temporary state during the process of breaking and forming bonds.
28
Fill in the blank: The rate of reaction is typically _____ at the beginning and decreases over time.
fastest
29
What is the effect of a higher concentration of reactants on the frequency of collisions?
It increases the frequency of collisions.
30
True or False: The energy needed to break bonds is always equal to the energy released when new bonds are formed.
False
31
What does a catalyst do to the energy profile of a reaction?
It lowers the activation energy barrier.
32
What can be measured to determine the rate of a reaction involving gas production?
The volume of gas produced over time.
33
Fill in the blank: In an exothermic reaction, the products have _____ energy than the reactants.
lower
34
What is the effect of adding an inert gas to a reaction mixture at constant volume?
It does not affect the reaction rate.
35
True or False: The bond energies of different types of bonds can vary significantly.
True
36
What is the primary factor that affects the rate of a reaction involving solids?
Surface area of the solid reactants.
37
Fill in the blank: A reaction is said to be _____ if it releases energy to the surroundings.
exothermic
38
What does the term 'rate constant' refer to in chemical kinetics?
A proportionality constant that relates the rate of a reaction to the concentration of reactants.