Energy and Enzymes Flashcards

1
Q

Define enzyme

A

a catalyst that speeds up chemical reactions

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2
Q

what enzyme catalyses the removal of a phosphate group from most molecules

A

phosphotase

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3
Q

What is the central mechanism for most intracellular communication

A

removal of a phosphate group

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4
Q

What type of reactions do enzymes play a key role in

A

Metabolic reaction (eg. growth, reproduction, respond to stimuli, movement)

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5
Q

Define energy

A

the capacity to do work or transfer heat

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6
Q

what is the kinetic energy of electricity

A

flow of e-

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7
Q

what is kinetic E

A

the E of movement; the E possessed by and object in motion

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8
Q

Define potential energy

A

E stored in objects giving them the capacity for work; E an object has bc of its chemical structure or position

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9
Q

Where is Ep stored within mlcls

A

within bonds between atoms of that moleculew

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10
Q

As e- move closer to the atomic nucleus, the atom…

A

loses Ep

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11
Q

What is the first law of thermodynamics

A

Energy can be transformed from one form to another but it cannot be created or destroyed

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12
Q

what is the second law of thermodynamics

A

every energy transfer or transformation makes the universe more disordered or increases entropy

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13
Q

define entropy

A

the tendency of energy to become dispersed and spread out

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14
Q

Biological systems transfer E from what two main sources?

A

light and catabolism

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15
Q

what is the main E driver in biological systems

A

photosynthesis

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16
Q

define Catabolism

A

the chemical breakdown of organic and inorganic molecules

17
Q

define enthalpy

A

the heat content of a system (△H)

18
Q

△H=

A

△Hproduct - △Hreactant

19
Q

enthalpy reflects

A

the number and kinds of chemical bonds that exist between atoms

20
Q

what is the overall △H of an endothermic reaction

21
Q

what is the overall △H of an exothermic rxn

22
Q

define spontaneous rxn

A

a reaction in which free E of the products is less than free E of the reactants

23
Q

Spontaneous rxns tend to occur when…

A

a) reactions are exothermic

b) △Sproducts > △Sreactants

24
Q

Entropy is increased when…

A

a) chem rxns result in an increase to the number of mlcls

b) when solids turn to liquids or when liquids turn to gas

25
Define free energy (△G)
the portion of a systems energy that can perform work when temperature is uniform throughout the system
26
△G=
△H-T△S
27
Define exergonic reaction
reaction where the free energy of the reactants ism greater than the free energy of the products
28
in exergonic rxns, is△G neg or pos
neg
29
are exergonic rxns energy consuming or energy releasing
energy consuming
30
what is another term for spontaneous reaction
exergonic process
31
define endergonic reaction
reaction where the free energy of the products is greater than the free energy of the reactants
32
In endergonic reactions is △G pos or neg
pos
33
are endergonic rxns energy consuming or energy releasing
consuming
34
Do endergonic or exergonic rxns result in a higher state of free E
endergonic rxns
35
what is the basis of an energy coupling rxn
production of E from exergonic rxn is available to run an endergonic rxn
36
do rxns tend to be more spontaneous when △S is pos or neg?
pos
37
define equilibrium
maximum stability of a rxn where △G=0, concentrations aren't necessarily equal