Energetics Flashcards
What are standard conditions
100 kPa
298k
Define endothermic
Positive energy change
Define exothermic
Negative energy change
Define enthalpy change of combustion
Enthalpy change of one mole of a substance burnt completely in excess oxygen to form CO2 and water in standard conditions and standard states
Enthalpy change of neutralisation
Enthalpy change of an acid base reaction producing one mole of water where all reactant are in standard states/ conditions
Calculating enthalpy change of neutralisation
-q/ mol of water
Mean bond enthalpy
Enthalpy change requires to break one mole of bonds under standard conditions with all reactants in the gaseous state
(AVERAGE)
General equation for energy change
Total energy absorbed- total energy released
Arrow direction in enthalpy of combustion
Away from reactants/ products
Arrow direction in enthalpy of formation
Towards the reactants and products
Problems with calorimetry
Heat loss to surrounding, calorimeter should be insulated
Sometimes combustion is incomplete, less energy given out
Flammable liquids usually volatile, lost fuel to evaporation
Gibbs free energy equation
Delta G= Delta H -(T x Delta S)