Energetics Flashcards

1
Q

What is an exothermic reaction

A

A reaction in which produces heat

-eg combustion, respiration or neutralisation

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2
Q

What is an endothermic reaction

A

Reaction that absorbs/requires heat to occur

-E.g. evaporation (heat the water) ice cube melting, heat is absorbed while melt

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3
Q

What is energy measured in

A

Kj

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4
Q

Is bond breaking is exothermic or endothermic

A

It’s endothermic because to break bonds you have to put energy in which is endothermic

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5
Q

Is making bonds exothermic or endothermic

A

It’s exothermic because energy is given back when bonds are made

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6
Q

What is bond enthalpy

A

The average energy required to break one mole of a stated bond

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7
Q

How do you work out the bond enthalpy

A

?H= energy products - energy react
So
?H = bonds broken - bonds made

Where ? means change in

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8
Q

If ?H = -ve, is the bond exothermic or endothermic

A

Exothermic as it had lost heat

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9
Q

If ?H = +ve, is the bond exothermic or endothermic

A

Endothermic because products have more energy than reactants

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10
Q

How does a endothermic energy profile diagram look

A

Energy of reactants (first line) is below energy of products (second line)

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11
Q

What does an exothermic energy profile diagram look like

A

Energy reactants (first line) is above energy of products (second line)

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12
Q

Which bit is the activation energy on a energy profile diagram

A

The distance from the first line to the peak of the graph

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13
Q

What is the energy absorbed on an energy profile diagram

A

The distance from the second line to the point at where the first line is

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14
Q

What are the 3 methods to find the enthalpy

A

1) ?H = Hproducts - Hreactants
2) ?H = bonds broken -bonds made
3) ?H = mc?t / h

1&2 are theoretic
3 is experimental

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15
Q

How do you work out the heat released

A

Q= MC?T

Q= heat release (joules)
?T= difference in temp. (T2-t1)
M=mass of water
C=specific heat capacity (418J per g per •c

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16
Q

What is equilibrium

A

It is when the system is balanced

? = reversible reaction. Goes forward and backwards at the same time. Eg ice melting ? water freezing

17
Q

What are the two types of equilibrium

A
  • Static equilibrium

- Dynamic equilibrium

18
Q

Define static equilibrium

A

When equilibrium is achieved and there is no net movement

19
Q

Define dynamic equilibrium

A

When do you rate (speed) of the forward reaction is equal to the rate of the reverse. The net change is zero. Note: if the forward reaction is endothermic, the reverse reaction is exothermic

20
Q

What must happen for there to be a reversible reaction

A
  • It must be a closed system

- (In dynamic) the rates of both ways of the reaction must be equal

21
Q

What is the Le chatelier principle

A

When a change is exerted on a system (chemical reaction) in dynamic equilibrium, the POE moves to do the exact opposite

22
Q

What is the POE affected by

A
  • Temperature
  • Concentration of reactants
  • Pressure of reactants
23
Q

What will increase in temperature due to the position of equilibrium

A

It will move to the endothermic side which absorbs heat.

24
Q

What will increase the concentration due to the position of equilibriums

A

It will move from left to right to remove excess reactants

25
Q

What will an increase in pressure due to the POE

A

It will move to the side with the fewest molecules (the one with the lowest pressure)

26
Q

What is H+ produced by

A

Any acid

27
Q

What is OH- produced by

A

Any alkali

28
Q

What does BENDO MEXO mean

A

Bonds broken = endothermic

Bonds made = exothermic

29
Q

In a closed system, can a reversible reaction reach an equilibrium

A

Yes

30
Q

What is energetically

A

Energetics is the energy change that takes place with the surroundings during a chemical reaction

31
Q

What do you methane and chlorine reacts to produce and what must be there for them to react

A

They react in the presence of ultraviolet light to reduce chloromethane and hydrogen chloride

32
Q

What is the equation for the haber process

A

N2 + H2 –> 2NH3

–> +ve

33
Q

Which catalyst is used in the haber process

A

Iron fillings

34
Q

What are the three raw materials used in the Haber process

A

Natural gas, air and water

35
Q

What is a by-product of the Haber process

A

Carbon dioxide

36
Q

What is the equation for the haber process

A

N2 + H2 –> 2NH3

–> +ve

37
Q

Which catalyst is used in the haber process

A

Iron fillings

38
Q

What are the three raw materials used in the Haber process

A

Natural gas, air and water

39
Q

What is a by-product of the Haber process

A

Carbon dioxide