Energetics Flashcards

1
Q

What is an exothermic reaction

A

A reaction that gives out energy usually in the form of heat

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2
Q

How would an exothermic reaction usually show itself

A

A rise in temperature in the surroundings

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3
Q

What is an endothermic reaction

A

A reaction that takes in energy from the surroundings usually in the form of heat

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4
Q

How would an endothermic reaction usually show itself

A

A fall in temperature in the surrounding

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5
Q

What is the overall change in energy in a reaction known as?

A

Enthalpy Change (kJ/mol)

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6
Q

What happens to the enthalpy change when the reaction is eXothermic

A

The result is negative

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7
Q

If an enthalpy change has a positive value what kind of reaction is it?

A

Endothermic (taking in energy)

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8
Q

What are reaction profiles / energy level diagrams

A

Shows the energies of the reactants and the products and how the energy changes over the course of the reaction

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9
Q

How would you label the axis in a energy level diagram

A

X - Progress of reaction Y - Energy

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10
Q

What is calorimetry

A

Allows you to measure how much energy is transferred in a chemical reaction

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11
Q

How do you measure dissolving and displacement reactions?

A

Take the temperature of the reactants, making sure they’re the same
Mix them in a polysteryene cup
Try to reduce the amount of energy lost to the surroundings by putting a lid on it
Measure the solution at the end of the reaction

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12
Q

How do you measure the energy transferred in a neutralisation reaction?

A

Put the same amount of each reactant into separate beakers
Place them in a water bath until they’re the same temperature
Add both reactants to a polystyrene cup with a lid
Take the temperature every 30 seconds and record the highest temperature

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13
Q

How do you measure the energy transferred in a combustion reaction

A

Record the water temperature
Weight the spirit burner and the lid
Heat the water in a copper container using the spirit burner, making sure you reduce the draughts with a screen
Stir it until the temperature is around 50 degrees celsius
Measure the temperature of the water
Weight the spirit burner and the lid again

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14
Q

How do you calculate the heat energy transferred

A

Q = m x c x ΔT

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15
Q

How do you work out the molar enthalpy change

A

Calculate heat tranferred (Q = m x c x ΔT)
Work out change in mass of the spirit burner
Work out how much 1g of fuel produces in terms of energy (kJ)
Work out number of moles (mass(g)/RFM)
Work out enthalpy change (energy transferred/num moles)

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16
Q

What is water of crystalisation

A

Water in a salt lattice of positive and negative ions

17
Q

What is a solid salt containing water of crystalistation

A

Hydrated

18
Q

What is a salt that doesnt contain and water of crystalisation

A

Anhydrous

19
Q

How would you calculate how much water of crystalisation a salt contains using experimental data?

A

Work out mass of hydrated product
Work out mass of anhydrous product
Calculate number of moles of water lost
Calculate number of moles of anhydrous salt
Work out ratio of moles of anhydrous salt to moles of water (must be a whole number)
Write with a dot in between (e.g. MgSO4.7H20)

20
Q

How can you find the data for an empirical formula using combustion

A

Heat a crucicle until its red hot to make sure its clean
Leave to cool, then weigh it
Add clean magnesium ribbon, reweigh
Heat crucible, put the lid on so that no bits of solid escape but oxygen can still enter
Heat for 10 min
Allow to cool, reweigh

21
Q

How can you find the data for an empirical formula using reduction

A

Place rubber bung into test tube and weigh
Take bung out and spread a small amount of copper ii oxide in middle of tube
Re-insert bung and weigh
Expel air by turning on gas, after 5 secs, light gas
Use bunsen burner to heat copper ii oxide for 10 mins
Turn off bunsen and leave to cool
Turn off gas and weigh