ELELCTRONEGATIVITY AND POLARITY Flashcards
Electronegativity is
The ability of an atom to attract electrons in a covalent bond .
pauling values are
used to compare electronegativity
electronegativity increases
!. going up a group
2. across a group
differances in electronegativity (3)
!. if the differance is less than 0.5=NON POLAR COVALENT BOND
2.if the differnace is between 0.5-2.7= POLAR COVALENT BOND
3.If the differance is above 2 = IONIC BOND
Electromegativity increases across a period due to
- charge on the nucleus
- increased attraction for the outer electron
electronegativity increases u a period due to
- number of shells increasing
- distance of the outer electrons from nucleus increases
Dipole means
a bond or molecule whose poles have opposite charges
polar bond
two bonding atoms are different air of electrons are distributed unequally
Non-polar bond
two bonding atoms are identical and electrons are equally distributed
H20 Is a
polar molecule due to the ermanent dipole
CO2 is a
Non-polar molecule containing a permant dipole
non-symetrical molecule properties
- a differnece in charge exists across the molecule
- overall dipole (slight differance in charge)
- the molecule is polar
Symetrical molecule properties
!. the symmetry of the molecule means the effect of the permanent dipole is cancelled
2. linear,trigonal planar and tetrahedral are all symetrical structures
3. all atoms are Non-polar
Permanent dipole
dipole in a polar covalent bond which does not change
molecules are non-polar if
symmetricla
molecules are polar if
asymmetrical
Intermolecular forces
Are weak attractions between dipoles of different molecules
Intermolecular forces are responsible for
Physical properties ( melting and boiling point )
Bond enthalpy
Amount of energy required to break the covalent bond
London forces
Are weak intermolecular forces that act between induced dipoles .
In London forces the movement of electrons
Produces a changing dipole in a molecule . The position is constantly changing
In London forces the more electrons in each molecule
Produces a larger instantaneous dipole