Electronic Properties Flashcards
what is a conjugated double bond
single (sigma) and double (pi) bonds alternate which leads to delocalization of electrons
(belong to a region/group of atoms not a single one)
what does the delocalization of electrons lead to
increase in stability of compound
- due to similar bond length between sigma and pi bonds
What does the decrease in symmetry of MO mean?
higher energy
What are resonance structures
the alternating structures of a compound (that it can exist in)
What are the rules for generating resonance structures
- movement of electron pairs only (between structures)
- the less charged, the more favourable
- no similar charges on adjacent atoms
- negative charges on electronegative atoms favoured
- delocalization max in planar system possible
can the bonds be different to each other in a carbon ring?
(unless there are double bonds) the bonds are all identical in a ring
Draw the resonance structures of benzene
What are two allotropes carbon
graphite and diamond
Why is the Benzene structure from Hückels proposal so stable?
they have overlapping p orbitals. This means that there are dense electron clouds above and below the horizontal axis
Do orbitals alway have to have electrons in them?
no. they can be vacant
Where can electrons be found in an orbital?
anywhere except in a node. (in p orbital one electron can be on either side but not in the middle
are orbitals interrelated?
No. ther are superimposed. 1s orbital is not middle part of 2s for example. (they are separate)
When is a compound considered aromatic?
when it follows Hückel rules:
- # of pi electrons has to be 4N+2 (N=0,1,2,..)
- molecule is planar
- conjugated pi system
- possible charges have tobe delocalized
What is tautomerism?
(constitutional isomers)
An reaction that simply. involes the intramolecular transfer of a protein
real fast equilibrium between two isomers
name and draw 3 examples of an aromatic compound