electronegativity Flashcards
define electronegativity
a measure of the tendency of an atom to attract a bonding pair of electrons in a covalent bond
GREATER ELECTRONEGATIVITY = MORE IT ATTRACT ELECTRONS TO IT
what are the 3 factors that affect how electronegative an atom is
- atomic charge
- atomic radius (distance from nucleus)
- electron shielding
if there is a bond between identical atoms what does this mean in terms of electrons
bonds between identical atoms = electrons are shared equally
if there is a bond between different atoms what does this mean in terms of electrons?
the more electronegative atom will have a greater share of the electrons
what type of molecule are symmetrical molecules even if they have polar bonds
non polar
if the difference in electronegativity is greater what does this do to the strength of the permanent dipole
the difference in electronegativity is greater = greater the strength of the permanent dipolr
what is the most electronegative atom
fluorine
what is the least electronegative atom
francium
why does electronegativity increase across a period
- the same amount of shielding
- atomic radius is increasing
- more protons
= higher electronegativity
why does electronegativity decrease down a group
shielding is increasing
atomic radius is decreasing
more protons
lower electronegativity
if there is no difference in electronegativity name the bond and give an example
non polar covalent bond
Cl-Cl
(electronically symmetrical)
if there is a small difference in electronegativity name the bond and give an example
polar covalent bond
H-Cl
(partial charges represented by delta)
if there is a large difference in electronegativity name the bond and give an example
ionic bond
Cl-Na
(full charges)
why does atomic radius decrease when going to the right of the periodic table
This is because new electrons get added to the same shell while going from left to right in a period, which increases the attraction between electrons and protons, thus pulling electrons closer to protons and decreasing the atomic radius.