Electron Configuration Flashcards

1
Q

Max Planck

A

1900, German. Man who said, “Light travels in tiny packets of energy that I’ll call quanta.” (1= quantum).

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2
Q

quantum

A

Minimum quantity of energy lost or gained by electrons.

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3
Q

Albert Einstein

A

1905, German. He renamed quanta to photons and suggested that they acted both like waves and particles. He used Planck’s quanta idea to explain the photoelectric effect.

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4
Q

Niels Bohr

A

1913, Danish. He explained the line spectra of hydrogen, by theorizing that maybe electrons are only allowed certain amounts of energy (like photons), meaning that they could only be found in certain energy levels around the nucleus.

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5
Q

Ground & excited state

A

When an atom is energized, the electrons jump to a higher level (excited state), but they don’t have enough energy to stay there so they fall back down (ground state).

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6
Q

Release of light

A

When electrons jump from ground to excited state, they release extra energy as light. The color of the light emitted depends on which orbit the electron from and to.

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7
Q

Louis deBroglie

A

1924, French. He said that if light acts like both a wave and a particle, maybe fast moving electrons can also act like waves as they go around the nucleus.

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8
Q

Werner Heisenburg

A

1927, German. Made the Heisenburg Uncertainty Principle.

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9
Q

Heisenburg’s Uncertainty Principle

A

It’s not possible to measure both the speed and location of an electron at the same time because to measure either, you have to bounce a photon off an electron which changes the electron’s course. The act of measuring one messes up the other.

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10
Q

Edwin Shroedinger

A

1926, Austrian. Theorized that electrons travel in standing waves as they go around the nucleus. He put all equations for these ideas together and came up with one big equation called the Shroedinger Equation.

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11
Q

Standing waves

A

Stable waves that bend back on themselves.

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12
Q

Shroedinger Equation

A

Equation made by Edwin Shroedinger that explained the line spectra of all glowing gases and shows the probable shapes of where the electrons are at any one time as they go around the nucleus.

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13
Q

Dimitri Mendelev

A

Organized the first periodic table by atomic mass, which showed repeating characteristic properties.He left empty spaces and predicted new elements there.

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14
Q

Periodic Law

A

Physical and chemical properties of the elements are periodic functions of their atomic numbers.

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15
Q

Henry Mosley

A

Reorganized the periodic table by atomic number (# of protons).

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16
Q

Sir William Ramsey

A

Man who proposed the new group noble gases.

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17
Q

Alkali metals

A

Group One. Silvery appearance, very soft, highly reactive especially with air and water. It is not found alone in nature.

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18
Q

Alkaline earth metals

A

Group 2. Harder, denser, stronger, have higher melting points, less reactive than alkali metals but still too reactive to be found alone in nature.

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19
Q

Valence electrons

A

Electrons in the outermost energy levels, involved in chemical reactions and are shared, lost, or gained.

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20
Q

noble gases

A

Group 18, have 8 valence electrons which is a full octet and is very stable.

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21
Q

d & f blocks

A

Only 2 valence electrons because they are inside the s orbitals. Their atoms are extra stable if their d or f blocks are halfway or all the way full, so sometimes they’ll steal an electron from the outermost s orbital to make that happen.

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22
Q

electromagnetic spectrum

A

whole range of electromagnetic radiation

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23
Q

wavelength

A

distance between two crests of two adjacent waves

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24
Q

frequency

A

Number of waves that pass a given point in a certain amount of time

25
Q

photoelectric effect

A

When a single photon with at least minimum energy strikes a metal surface, an electron is ejected a certain distance depending on its strength. Different metals have different minimum energy. Discovered by Einstein.

SIMPLY PUT, it is the emission of electrons from a metal when light is shined on it.

26
Q

photon

A

Particle of electromagnetic radiation that has a quantum of energy

27
Q

Aufbau principle

A

As protons are added one by one to the nucleus to build up the atoms of the elements, electrons are similarly added to these atoms (to keep the atom neutrally charged) they fill the orbitals in accordance to the Pauli principle.

SIMPLY PUT, an electron occupies the lowest energy orbital that can receive it.

28
Q

electron configuration

A

the arrangement of electrons in an atom (tells in which energy levels they are located and the patterns they follow when orbiting the nucleus).

29
Q

Pauli exclusion principle

A

In a given atom, no two electrons may occupy the same place in the electron orbital diagram without having opposite spins. Spin is indicated in the electron orbital diagram by using arrows facing in opposite directions. Spin is indicated by the quantum number s (the spin quantum number), opposite direction is indicated by a -1/2.

SIMPLY PUT, no two electrons in the same atom can have the same set of four quantum numbers.

30
Q

Hund’s rule

A

The lowest energy (and stablest) arrangements of the electrons in an atom is one which has the maximum number of single electrons, allowed by the Pauli principle in a particular subshell. Notice that this related to electrons having a negative charge and that like charges repel.

SIMPLY PUT, orbitals of equal energy are occupied one electron before any orbital is occupied by a second electron, and all electrons in singly occupied orbitals must have the same spin.

31
Q

atomic radius

A

Half the distance between the nuclei of identical atoms that are bonded together.

32
Q

Size trend: left to right

A

Becomes smaller due to increased attraction of electrons due to more protons in the necleus

33
Q

Size trend: top to bottom

A

Becomes larger because of increased attraction of electrons due to more protons in the nucleus

34
Q

Exceptions to the size trends

A

d & f orbitals, lanthanides & actinides

35
Q

cation

A

A positive atom that has lost an electron(s)

36
Q

ion

A

When an atom loses or gains electron(s) it becomes an ion

37
Q

anion

A

A negative atom that has gained an electron(s)

38
Q

ionization energy

A

energy required to remove an electron from a neutral atom, measured in kj/mol, increases across periods due to higher nuclear attraction on electrons, decreases down groups because valence electrons are further from positive nucleus and more easily removed.

39
Q

electron affinity

A

energy change (gained/released) that occurs when an electron is acquired by a neutral atom, measured in kj/mol, generally increases left to right and from bottom to top.

40
Q

halogens

A

Group 17. Most reactive nonmetals, form salts with alkaline metals, gains electrons most easily

41
Q

f block elements

A

Lanthanides and actinides, between groups 2 & 3, actinides are radioactive, all but first four are lab made only

42
Q

d block elements

A

Groups 3-12, transition elements, typical metallic properties, not very reactive, some don’t form compounds

43
Q

The larger the molecule….

A

the less likely it is to attract an electron

44
Q

One cannot add ________ to negative ions to _______.

A

You can’t add electrons to negative ions to make them more negative.

45
Q

Cations become ____ across a period because…

A

Smaller because of the increased attraction of the additional protons in the nucleus

46
Q

anions become ____ than its atom because…

A

Larger due to the fact that its electrons are not as strongly attracted with an additional electron, and there’s a greater repulsion between electrons, decrease across periods in the groups 15-18

47
Q

electronegetivity

A

Measure of the ability of the atom in a chemical compound to attract electrons. Increases left to right and decreases or stays the same down groups.

48
Q

Do cations get bigger or smaller in their neutral atoms?

A

Smaller, less electrons results in a greater pull from the protons, which draw in the electrons closer to the nucleus. They also give off their outermost electron shell

49
Q

largest element

A

francium

50
Q

smallest element

A

hydrogen

51
Q

lightest element

A

hydrogen

52
Q

heaviest element

A

ununoctium

53
Q

Why is Fluorine the most electronegative element?

A

It is the smallest element that will attract electrons because Hydrogen gives up an electron and Neon and Helium are stable noble gases. There isn’t anything shielding the proton’s attractive force from electrons and it is furthest to the right (besides Neon) so it has the most protons to attract electrons.

54
Q

spin quantum number

A

the quantum number that only has two possible values, +1/2 and -1/2, which indicate the two spin states of an electron (which way they are facing).

55
Q

p block element shape

A

figure 8

56
Q

d block element shape

A

flower

57
Q

s block shape

A

circle

58
Q

f block shape

A

3d flower