Electrolysis glossary Flashcards

1
Q

electrolytic reaction

A

non spontaneous redox reaction that requires electricity for it to occur

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2
Q

electrolytic half equation

A

one of two equations (oxidation or reduction) which describes one half of an electrochemical reaction

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3
Q

molten electrode

A

melted ionic compound with ions that are free to move and in the liquid state

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4
Q

aqueous electrode

A

dissolved ionic compound with ions that are free to move and in the aqueous state

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5
Q

anode

A

positively charged electrode in an electrochemical cell where oxidation occurs

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6
Q

cathode

A

negatively charged electrode in an electrochemical cell where reduction occurs (remember: don’t electrocute the cat)

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7
Q

overpotential

A

difference between the calculated potential required and the actual potential required and the actual potential required and the actual potential required to facilitate an electrolytic reaction

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8
Q

Power supply

A

an electrical device such as a battery or a generator that provides electrical energy to a circuit

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9
Q

standard electrode potential

A

potential of the half-reaction (reduction) given in volts (V), relative to the standard hydrogen half cell

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10
Q

Coulombs {C}

A

unit used to measure the amount of electrical charge

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11
Q

Current (I)

A

rate of flow of electric charge (e-)

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12
Q

Electric charge (Q)

A

amount of charge (usually measured in Coulombs)

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13
Q

electroplating

A

application of electrolysis used to coat a substance with a metallic layer

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14
Q

Faraday’s constant (F)

A

total electric charge of 1 mol of e-, 96500Cmol-1

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15
Q

Amperes (A)

A

unit measures the amount of current

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16
Q

Faradays first law of electrolysis

A

the amount of current passed through an electrode is directly proportional to the amount of material released from it
Q=It

17
Q

Faraday’s second law of electrolysis

A

when the same quantity of electricity is passed through several electrolytes, the mass of the substances deposited are proportional to their respective chemical equivalent

18
Q

Hall-Heroult

A

the method of aluminium production used in primary aluminium smelters throughout the world

19
Q

Lead-acid accumulator

A

a battery with lead electrodes using dilute sulfuric acid as the electrolyte; each cell generates about 2 volts