Electrolysis Flashcards

1
Q

Definition of electrolysis

A

The passage of electricity through a chemical substance causing a chemical change and the formation of new substances at the electrodes

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2
Q

for the bulb to light there must be?

A

a complete circuit

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3
Q

Ionic substances dissolve in water to form what?

A

An aqueous solution

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4
Q

The ions in the ionic substance become what>

A

Mobile

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5
Q

if the aqueous solution is connected in a circuit what will happen?

A

an electric current will flow

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6
Q

The aqueous solution is an example of what?

A

An electrolyte

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7
Q

Give three examples of an aqueous solution

A

Sodium chloride solution
dilute sulphuric acid
copper sulphate solution

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8
Q

electrolysis of sodium chloride solution observation at the anode (positive electrode)

A

fizzing and chlorine smell

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9
Q

electrolysis of sodium chloride solution observation at the cathode (negative electode

A

hydrogen

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10
Q

half equation for oxygen

A

4OH(-) - 4E- = 02 + 2H(2)0

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11
Q

half equation for hydrogen

A

2H+ (+) 2E- = H2

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12
Q

What are the ‘rules’ for the anode (positive electrode)

A
  • halide ions always lose their electrons before hydroxide ions
  • hydroxide ions will lose their electrons before sulphate or nitrate ect
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13
Q

what are the ‘rules’ at the cathode?

A

metal ions below hydrogen in the reactivity series always gains electrons before H+ ions
-H+ ions always gain electrons before metal ions that are above it in the reactivity series

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14
Q

Definition of the electrolysis of brine

A

a very important electrolysis of concentrated sodium chloride solution used in the industry

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15
Q

what does the electrolysis of brine produce?

A
  • Chlorine Gas
  • Hydrogen Gas
  • Sodium Hydroxide Solution
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16
Q

What are the ions present in brine

A

Sodium
chlorine
hydroxide
hydrogen

17
Q

whats happens when an electrical current passes through brine at the cathode (-)

A

sodium and hydrogen ions move to the cathode
-H+ ions gain electrons and H+ gas is released
Na+ ions remain in solution

18
Q

What happens when an electrical current passes through brine at the Anode (+)

A
  • chloride and hydroxide ions move to the anode
  • chloride ions lose electrons and chlorine gas is released
  • hydroxide ions remain in solution
19
Q

What is made in the electrolysis of brine and at which electrode or other>

A
  • Hydrogen gas at the cathode
  • Chlorine Gas at the anode
  • sodium hydroxide solution left in the container
20
Q

What is Hyrogen Gas used for?

A
  • harden veg oil into margarine

- make hydrochloric acid for use in pharmacy industry

21
Q

What is chlorine gas used for?

A

(poisonous) -to kill bacteria in drinking water and pools
- to make bleach + pvc/plastics
- to make disinfectant

22
Q

what is sodium hydroxide solution used for?

A
  • soap
  • paper
  • bleach
23
Q

What is the test for hydrogen?

A

insert a lighted splint
gas burns with a pop
HAZARD- in air a spark causes explosion

24
Q

test for oxygen?

A

insert a glowing splint

the splint relights

25
Q

Test for carbon dioxide

A
  • bubble the gas through limewater

- the limiter turns milky

26
Q

test for chlorine

A
  • put damp BLUE litmus paper in the gas

- the litmus turns pink and then BLEACHES

27
Q

test for Ammonia

A

put red litmus in the gas
-the litmus turns blue the gas is alkaline
HAZARD= alkaline very soluble in water danger of suck back

28
Q

Hydrogen chloride test

A

put the gas ned to a bottle of ammonia solution

the gas gives dense white fumes of ammonium chloride

29
Q

test for water x2

A

add to anhydrous copper sulphate(white) add to blue cobalt chloride paper
-anyhydrous copper sulphate turns blue
blue cobalt chloride paper turns pink

30
Q

Test for pure water

A

boils at 100C

freezes at 0C

31
Q

test for Alkenes C=C double bonds (unsaturated hydrocarbons)

A

shake with bromine water

-bromine water decolourises turns from yellow/brown to colourless

32
Q

definition of an electrolyte

A

a liquid or gel which contains ions and can be decomposed by electrolysis, e.g. that present in a battery.

33
Q

definition of conductor

A

a metal that conducts electricity when it is solid as it does not have mobile ions

34
Q

In a circuit which way do the electrons go

A

negative to positive

35
Q

Why does solid Lead (II) not undergo electrolysis

A

It doesn’t have mobile ions

36
Q

Describe what you would observe in the electrolysis of lead (II)

A

lead- a shiny substance would form at the cathode and bromine gas and fizzing would be given off at the anode