Electrolysis Flashcards
Definition of electrolysis
The passage of electricity through a chemical substance causing a chemical change and the formation of new substances at the electrodes
for the bulb to light there must be?
a complete circuit
Ionic substances dissolve in water to form what?
An aqueous solution
The ions in the ionic substance become what>
Mobile
if the aqueous solution is connected in a circuit what will happen?
an electric current will flow
The aqueous solution is an example of what?
An electrolyte
Give three examples of an aqueous solution
Sodium chloride solution
dilute sulphuric acid
copper sulphate solution
electrolysis of sodium chloride solution observation at the anode (positive electrode)
fizzing and chlorine smell
electrolysis of sodium chloride solution observation at the cathode (negative electode
hydrogen
half equation for oxygen
4OH(-) - 4E- = 02 + 2H(2)0
half equation for hydrogen
2H+ (+) 2E- = H2
What are the ‘rules’ for the anode (positive electrode)
- halide ions always lose their electrons before hydroxide ions
- hydroxide ions will lose their electrons before sulphate or nitrate ect
what are the ‘rules’ at the cathode?
metal ions below hydrogen in the reactivity series always gains electrons before H+ ions
-H+ ions always gain electrons before metal ions that are above it in the reactivity series
Definition of the electrolysis of brine
a very important electrolysis of concentrated sodium chloride solution used in the industry
what does the electrolysis of brine produce?
- Chlorine Gas
- Hydrogen Gas
- Sodium Hydroxide Solution