Electrolysis Flashcards

1
Q

if the carbon method for extracting metals doesnt work, what do we use?

A

So, for metals that are MORE reactive than carbon (above carbon on the reactivity series) we use electrolysis

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2
Q

what is an ore how do we extract the metal normally

A

A metal ore is when a metal has reacted with other substances to form a rock (normally oxygen)

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3
Q

how do we extract the metal normally

A

To extract the metal the metal from this ore, we use displacement reactions. We react carbon with the metal ore, so that it displaces the metal, leaving us with just the metal and carbon dioxide.

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4
Q

what does electrolysis mean

A

Electro = electricity
Lysis = splitting
SO electrolysis = splitting something using electricity

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5
Q

what is the solution in electrolysis called

A

electrolyte

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6
Q

what is the pneumonic for the reactivity series

A

please stop calling me a careless zebrea instead try learn how copper saves gold

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7
Q

please stop calling me a careless zebrea instead try learn how copper saves gold

A

potassium
sodium
calcium
magnesium
aluminium
carbon
zinc
iron
tin
lead
hydrogen
copper
silver
gold
(platinum)

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8
Q

what type of compound can be used in electrolysis and why? (2)

A

Only ionic compounds can be used in electrolysis as they are the only ones that separate and can carry charge, and so can conduct electricity (when molten or aqueous), which is necessary in electrolysis

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9
Q

how does electrolysis work, what do the electrodes do and the electrical circuit (3)

A

charged ions are attracted to the electrodes of opposite charges where they get discharged (so they gain or lose the necessary amount of electrons at the electrode which makes them atoms again)
The electric circuit keeps the flow of electrons going

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10
Q

what is the order of discharge on each electrode

A

At the cathode, the least reactive substance gets discharged
At the anode the order of preference is halides, then hydroxide ions then anything else

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11
Q

what is the difference between halides and halogens

A

Halides are group 7 IONS, halogens are group 7 ATOMS

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12
Q

when writing formulae what is the big number infront of the compound and what is the little number within the compound

A

the big number at the front is how many lots of something there are. when you use the little number, it indicates that there is some bonding

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13
Q

how to check half equations

A

To check half equations:

Make sure you have drawn an arrow and not equals
Check that it’s balanced
Make sure that the overall charge on each side is equal

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14
Q

write the formula, which atom will be discharged at which electrode, and the half equations for
aqueous sodium chloride (3)

A

Formula: NaCl
Discharge:
Cathode ; H +1 ion
Anode ; Cl+1 ion
H2 —> e- + 2h+1
Cl2 + 2e- ——> 2Cl-1

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15
Q

what are the uses of aluminium (6)

A

Uses of aluminium:

cooking foil
cars
pans
overhead power cables
drink cans
windows

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16
Q

Why does aluminium extraction HAVE to be done using electrolytes:

A

Aluminium extraction can only be done using electrolysis because Aluminium is Above carbon so the carbon method cant be used for Aluminium extraction, thus electrolysis is used

17
Q

what is bauxite, its properties and how to obtain

A

Aluminium in its natural state is aluminium oxide which is found in an ore called bauxite
You get this ore by cast mining (digging it directly from the surface
Bauxite is mainly Al2O3 however it has impurities (iron oxide, so the waste solution is a rusty brown), so the first step in aluminium extraction is to extract the aluminium oxide from the impurities

18
Q

why do we have to use molten aluminium oxide in aluminium extraction

A

In aluminium extraction, you HAVE to use molten (l) aluminium oxide, not aqueous (aq), as with aqueous, hydrogen will be discharged at the cathode, but it’s aluminium which we want

19
Q

what do we do to keep the aluminium molten

A

We mix an ionic compound called cryolite with aluminium oxide to lower the melting point

20
Q

why do we need to replace the electrodes often in aluminium extraction

A

Oxygen reacts with hot carbon (graphite) electrodes to form CO2, and this means the electrodes need to be replaced quite often

21
Q
A