Electrochemistry Flashcards

1
Q

Gibbs free energy for spontaneous reaction

A
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2
Q

Recall contribution of enthalpy and entropy to spontaneity of change

A

Spontaneity for different values of
∆H, ∆S, ∆G

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3
Q

Recall thermodynamic relationships

A

VAT
UG
SHP

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4
Q

Work without compression/expansion

A

Non-PV work

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5
Q

Max non-PV work at constant TP

A

Gibbs free energy. Recall formula

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6
Q

Max non-PV work at constant TV

A

Helmholtz free Energy. Recall formula

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7
Q

Comversion of electrochemical energy to electrical energy, vice versa using ____

A

Electrochemical cells

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8
Q

Electrochemical cell that uses spontaneous reaction, thus cell potential is positive

A

Voltaic

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9
Q

Electrochemical cell taht uses a voltage source to drive non spontaneous redox having negative cell potential

A

Electrolytic cell

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10
Q

Oxidation occurs at

A

Anode

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11
Q

Reduction occurs at

A

Cathod

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12
Q

Recall the measure of electrical potential

A

Note. F has the highest electrical potential (standard red potentials) means very good oxidizing agent

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13
Q

Faraday’s law of electrolysis
First
Second

A

Mass of substance involved in an electrochemical reaction is directly proportional to currenta applied. Recall formula (mit norma fajardo)

Certain amount of electricity will result to same equivalents in same circuit. Recalm formula

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14
Q

Opposite of resistance. Ability of substance to allow the transport of charges

A

Conductivity

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15
Q

Recall series, parallel circuit. And ohms law formula

A
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16
Q

Measure of conductivity

A

Conductance. Recall formula

17
Q

Recall conductivity of metals

A

Temp up
G down

18
Q

Recall conductivity of electrolytes

A

Temp up
G up

19
Q

Higher mobility of ions higher conductivity

A

Strong electrolytes have higher conductivity

20
Q

Higher mobility of ions higher conductivity

A

Strong electrolytes have higher conductivity