Colligative Properties Flashcards
Properties of solution that are dependent on amount of solute and nature of solvent but independent on the nature of solute
Colligative properties
Solutions that do not form ions in solutions
Ideal
Solutions that form ions in solution in form of electrolytes
Non ideal
Effective concentration of non ideal electrolytes which heightens the interaction between the ions of the solute and the solvent
Activity
Accounts for deviation of electrolytes to normal behavior due to electrostatic interactions
Debye Huckel theory
Debye huckel limiting law (I<0.01)
Extended debye huckel law(0.01<I<0.1)
Davies equation (I>0.1)
Shows the ratio of actual to expected colligative property
Vant Hoff factor
Solute particles hinder the vaporization of the pure solvent
Vapor pressure lowering
Pressure needed to prevent transport of particles to more conc solution through semi perm membrane
Osmotic pressure (osmometry)
Shows increased interaction between the solute and solvent particles, increasing the temp needed to boil as compared to that of oure solvent
Boiling point elevation (ebullioscopy)
Shows increased interaction between the solute and solvent particles, decreasing the temp needed to attain the solid crystal structure as compared to that of pure solvent
Freezing point depression (cryoscopy)