electrochemistry 🛁 Flashcards
which electrode is the cathode and anode?
positive electrode: anode
negative electrode: cathode
describe what happens at each anode
__ ions migrate towards the cathode. __ ions are discharged where they gain/lose electrons to form __
what ions are present in aqueous solution?
H+, OH-, ions from compound
what factors affect the ion preferentially discharged?
1) relative position of ions in the electrochemical series
2) concentration of electrolyte
3) nature of electrodes
which ions will be preferentially discharged if present in a concentrated electrolyte?
lead, iron, zinc, iodide, bromide, chloride
describe the process of preferential discharge (H+ and Na+)
sodium ions and hydrogen ions are attracted to the cathode. hydrogen ions are preferentially discharged because they gain electrons more easily to produce hydrogen gas
describe what happens when copper electrodes are used
__ ions are attracted to the anode. however, both ions are not discharged, instead the copper anode, being a reactive anode, itself loses electrons. coper in the anode loses electrons to produce copper (II) ions which go into the electrolyte
why does the copper(II) sulfate electrolyte not fade when using copper electrodes?
for each copper(II) ion discharged, another one is formed at the anode which goes into the solution, hence concentration of copper(II) ions stay the same
applications of electrolysis
1) purification of copper
2) electroplating
describe electron flow in a simple cell
electrons flow from the more reactive metal to the less reactive metal
which electrodes are positive and negative and what ions do they attract?
more reactive metal: negative electrode
less reactive metal: positive electrode, attracts cations
what reaction occurs at the zinc terminal? (zn and cu)
Zn -> Zn2+ + 2e-
what reaction occurs at the copper terminal?
2H+ + 2e- -> H2
briefly describe fuel cells
reactants are continuously supplied to produce electricity directly (2H2 + O2 -> H2O)
advantages of fuel cellss
water is produced as the waste product, which can be drank by astronauts in space