EL 7 - Blood, sweat, and seas Flashcards
What reactants produce magnesium sulfate?
sulfuric acid + magnesium
What reactants produce lithium chloride?
hydrochloric acid + lithium oxide
What reactants produce barium sulfate?
barium chloride + magnesium sulfate
What reactants produce sodium ethanoate?
ethanoic acid + sodium carbonate
What reactants produce ammonium nitrate?
nitric acid + ammonium hydroxide
Give an example of a use of magnesium sulfate
bath salts
Give an example of a use of lithium chloride
lithium batteries
Give an example of a use of barium sulfate
‘barium meal’ shows up soft tissue on x-ray
Give an example of a use of sodium ethanoate
hand warmers
Give an example of a use of ammonium nitrate
fertiliser
Name all of the period 3 elements (in order)
Na, Mg, Al, Si, P, S, Cl and Ar
What do Na and Mg oxides (basic oxides) produce when they are added to water?
An alkali
How can aluminium oxide be described (what type of oxide)?
An amphoteric oxide - can react with acids/alkalis
What do Al and Si oxides produce when added to water?
The products are the same as the reactants as both Al and Si oxides don’t dissolve in water
What type of oxides are Na and Mg oxide?
basic oxides
What types of oxides are Si, P, S and Cl oxide?
acid oxides
What do Si, P, S and Cl oxides produce when they are added to water?
An acid
Define electronegativity
The tendency of an element to attract electrons in a covalent bond
How would you describe the difference in the electronegativity of ionic bonds?
Big difference in electronegativity
How would you describe the difference in the electronegativity of polar covalent bonds?
Medium
How would you describe the difference in the electronegativity of covalent bonds?
Small
What does an oxyanion consist of?
XOy^z-
X: another element
y: no. of oxygen atoms
z-: negative ion
What is the difference between a cation and an anion?
Cation: positive ion
Anion: negative ion
What products are made from acid + alkali?
salt + water
What products are made from acid + base?
salt + water
What products are made from acid + carbonate?
salt + water + carbon dioxide
What products are made from acid + metal?
salt + hydrogen
Many ionic substances dissolve in water but which ones don’t?
- barium, calcium, lead and silver sulfates
- silver + lead halides
- all metal carbonates
- metal hydroxides (except group 1 and ammonium hydroxides)
What happens when ionic substances dissolve and what does this allow them to do?
The ions become surrounded by water molecules and spread out through the solution.
Once separated, behave independently of each other.
This presence of hydrated ions in solution explains why aqueous solutions of salts can conduct electricity.
What are spectator ions?
The ions that are non involved in the reaction (+ not part of the ionic equation)
What is ionic precipitation?
A suspension of solid particles is produced by a chemical reaction in solution
Name the solution that is added to Cu2+, the name of the precipitate formed and what colour it is
Solution added: sodium hydroxide
Precipitate formed: copper hydroxide
Colour of precipitate: blue
Name the solution that is added to Fe2+, the name of the precipitate formed and what colour it is
Solution added: sodium hydroxide
Precipitate formed: iron (II) hydroxide
Colour of precipitate: (dirty) green
Name the solution that is added to Fe^3+, the name of the precipitate formed and what colour it is
Solution added: sodium hydroxide
Precipitate formed: iron(III) hydroxide
Colour of precipitate: orange/brown
Name the solution that is added to Pb^2+, the name of the precipitate formed and what colour it is
Solution added: potassium iodide
Precipitate formed: lead iodide
Colour of precipitate: bright yellow
Name the solution that is added to Cl^-, the name of the precipitate formed and what colour it is
Solution added: silver nitrate
Precipitate formed: silver chloride
Colour of precipitate: white
Name the solution that is added to Br^-, the name of the precipitate formed and what colour it is
Solution added: silver nitrate
Precipitate formed: silver bromide
Colour of precipitate: cream
Name the solution that is added to I^-, the name of the precipitate formed and what colour it is
Solution added: silver nitrate
Precipitate formed: silver iodide
Colour of precipitate: pale yellow
Name the solution that is added to SO4^2-, the name of the precipitate formed and what colour it is
Solution added: barium chloride
Precipitate formed: barium sulfate
Colour of precipitate: white
Give the ionic equation of Cu and sodium hydroxide
Cu^2+(aq) + 2OH^-(aq) -> Cu(OH)v2(s)
Give the ionic equation of sulfate and barium chloride
Ba^2+(aq) + SOv4^2- -> BaSOv4(s)
Give the ionic equation of iodine and silver nitrate
Ag^+(aq) + I^-(aq) -> AgI(s)
What shape do ionic compounds often form?
lattice + regularly shaped crystals
What substances have an ionic structure?
Compounds of metals with non-metals
What substances have a covalent network structure?
Some elements in group 4 and some of their compounds
What substances have a metallic structure?
Metals
What substances have a simple molecular structure?
Some non-metal elements and some non-metal/non-metal compounds
What substances have a macromolecular structure?
Polymers
Give an example of a compound that has an ionic structure
NaCl and CaO
Give an example of a compound that has a covalent structure
Diamond, graphite and silica
Give an example of a compound that has a metallic structure
Na, Cu and Fe
Give an example of a compound that has a simple molecular structure
COv2, Clv2 and Hv2O
Give an example of a compound that has a macromolecular structure
poly(ethene), nylon, proteins and DNA
What type of particles does an ionic structure contain?
ions
What type of particles does a covalent network contain?
atoms
What type of particles does a metallic structure contain?
positive ions surrounded by delocalised electrons
What type of particles does a simple molecular structure contain?
small molecules
What type of particles does a macromolecular structure contain?
long-chain molecules
How are the particles bonded in an ionic structure?
Strong ionic bonds - attraction between oppositely charged ions
How are the particles bonded in a covalent structure?
Strong covalent bonds - attraction of atom’s nuclei for shared electrons
How are the particles bonded in a metallic structure?
Strong metallic bonds - attraction of atom’s nuclei for delocalised electrons
How are the particles bonded in simple molecular structure?
Weak intermolecular bonds between molecules - strong covalent bonds between the atoms within molecules
How are the particles bonded in a macromolecular structure?
Weak intermolecular bonds between the atoms within molecules - strong covalent bonds between the atoms within the molecules
What are the typical properties/boiling or melting points of ionic, covalent (network), metallic, simple molecular and macromolecular structures?
Ionic: high
Covalent (network): very high
Metallic: generally high (except mercury)
Simple molecular: low
Macromolecular: moderate - often decompose on heating
What is the hardness of an ionic, covalent (network), metallic, simple molecular and macromolecular structure?
Ionic: hard but brittle
Covalent (network): very hard (if three-dimensional)
Metallic: hard but malleable (except mercury)
Simple molecular: soft
Macromolecular: variable - many are soft but often flexible
What is the electrical conductivity of ionic, covalent (network), metallic, simple molecular and macromolecular structures?
Ionic: electrolytes conduct when molten or dissolved in water
Covalent (network): do not normally conduct (except graphite)
Metallic: conduct when solid or liquid
Simple molecular: do not conduct
Macromolecular: do not normally conduct
What is the solubility of an ionic, covalent (network), metallic, simple molecular and macromolecular structure like in water?
Ionic: often soluble Covalent (network): insoluble Metallic: insoluble (but some react) Simple molecular: usually insoluble, unless molecules contain groups which can hydrogen bond with water Macromolecular: usually insoluble
What is the solubility of an ionic, covalent (network), metallic, simple molecular and macromolecular structure like in non-polar solvents (e.g hexane)?
Ionic: insoluble Covalent (network): insoluble Metallic: insoluble Simple molecular: usually soluble Macromolecular: sometimes soluble