EE Lecture 23: Nitrogen Flashcards

1
Q

what is often the most limiting nutrient for plant growth

A

nitrogen -aas,proteins,enzymes

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2
Q

give an example of how nitrogen is an essential part of many defensive chemicals

A

alkaloids

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3
Q

what is formula for nitrateq

A

NO3-

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4
Q

what is formula for nitrite

A

NO2- (has 2 i’s therefore 2 Os)

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5
Q

what is formula for nitrous oxide

A

N20

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6
Q

how many orders of magnitude difference between nitrogen pools? give examples of N pools

A

atm
soils and orgs
4 orders of magnitude difference

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7
Q

outline some fluxes of Nitrogen

A
biomass
N uptake by roots
N excretion
Nitrification
Denitrification
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8
Q

how/when is nitrogen lost

A
with years of cultivation
at increased temperatures
by conversion to nitrate followed by leaching
fire - biomass combustion
lost to sediments as well
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9
Q

what does the high turnover of nitrogen in living tissues suggest about storage

A

high turnover of nitrogen in living tissues suggests low storage potential in eqb,

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10
Q

what is stage one of nitrogen cycle

A

oxidation of ammonia to nitrite inside cells of Nitrosoccus bacteria

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11
Q

what bacteria cause oxidation of ammonia

A

Nitrosoccus cause oxidation of ammonia to nitriteq

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12
Q

what do Nitrosoccus bacteria do

A

oxidation of ammonia to nitrite

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13
Q

what is stage 2 of nitrogen cycle

A

oxidation of nitrite to nitrate by Nitrobacter bacteria

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14
Q

what does Nitrobacter do

A

oxidise nitrite to nitrate

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15
Q

what bacterium oxidises nitrite to nitrate

A

nitrobacter

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16
Q

what is the sole energy source of nitrobacter and nitrosoccus
what is it used for

A

oxidation is the sole energy source of these bacteria, used for chemosythetic assimilation of CO2

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17
Q

what do nitrobacter and nitrosoccus do with the energy source from oxidation

A

they use it for chemosynthetic assimilation of CO2

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18
Q

when/how does nitrate act as an oxidising agen

A

in the absence of oxygen, nitrate may act as an oxidising agent

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19
Q

what condns needed for nitrate to act as oxidising agent

A

anaerobic

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20
Q

how does nitrate act in anaerobic condns

A

as an oxidising agent

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21
Q

how does nitrate act as an oxidising agen

A

gets reduced to nitrite by accepting a hydrogen acceptor

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22
Q

what does nitrate get reduced to - how

A

nitrate gets reduced to nitrite by accepting a hydrogen

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23
Q

under what condns does nitrate get reduced to nitrite

A

anaerobic condns

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24
Q

what is it called when nitrate gets reduced to nitrite

A

denitrification

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25
name some nitrogen fixing bacteria
Azotobacter, Clostridium, Rhizobium
26
what are Azotobacter, Clostridium and Rhizobium all examples of
nitrogen fixing bacteria
27
name some nitrogen fixing blue green algae
Nostoc Anabena Cylindrospermum
28
name some nitrogen fixing actinomycetes
Frankia on tree roots
29
when does nitrogen fixation by nodulating bacteria stop
fixation by nodulating bacteria stops when fertiliser nitrogen is applied, because plants stop feeding the bacteria
30
why does nitrogen fixation by nodulating bacteria stop when nitrogen fertiliser is applied to the plant
because plants stop feeding the bacteria carbohydrate, as it does not need the bacteria for nitrogen fixing
31
at what soil pH does nitrogen fixation stop in plants
when pH falls below 4
32
what form is nitrogen in in soil mostly?
97098% stable organic compounds half as protein N half as amino sugars,chitin,lignin
33
how is soil nitrate lost quickly
by leaching
34
what is leaching
loss of soil nitrate
35
which form of ammonia has longer retention
ammonia (compared to nitrate)
36
give an example of something with high carbon, low nitrogen ratio
wood
37
what is the result of a high carbon low nitrogen ratio
slow decomposition low food quality long residence time in soil
38
give an example of something with a high carbon nitrogen ratio
young leaves or meat
39
what is the result of having a low carbon:nitrogen ratio
high food quality | rapid decomposition
40
what does slow decomposition, low food quality and long residence time in soil suggest about the carbon:nitrogen ratio
high carbon low nitrogen eg.wood
41
what does high food quality and rapid decomposition suggest about the carbon:nitrogen ratio
low c:n ratio
42
what species are involved in nitrogen fixation in deserts
lichens of the desert crust
43
what do lichens in the desert crust do
fix nitrogen
44
how can nitrogen pollute the enviro
leaching into groundwater marine pollution from sewage and other terrestrial inputs movement of gaseous ammonia globally
45
which ecosystems have the highest critical load of N
most terrestrial ecosystems
46
which ecosystems are extremely sensitive and have a small critical load of N
soft water lakes and ombrotrophic mires
47
how much of the nitrogen used in producing food do people eat?
only 10%
48
what is the ratio of fertilizer input to N in product
3 wheat 14 dairy 21 meat
49
which food product has the most fertilizer N put into it
21 meat (3 wheat 14 dairy)
50
what are some atmospheric sources of nitrogen pollution
industry vehicle exhausts farm animals fertilizer dusts
51
what is the park grass experiment
the longest running ecological experiment in the world - used to determine the optimal fertilizer regime for hay yield
52
how and why are nitrogen and carbon cycles tightly coupled
coupled through processes of photosynthesis and decomposition because N is one of the resources that most commonly limits primary production
53
what is the largest pool of N
atmospheric dinitrogen gas
54
what shows that anthropogenic fluxes are now dominant components of the N cycle
the rate of fixation of atmospheric N2 by humans exceeds the rate of natural terrestrial biological fixation
55
what are the main anthropogenic nitrogen fluxes
``` Haber-Bosch process growing crops -soybeans,alfafa and peas that have symbiotic relationships with nitrogen fixing bacteria fossil fuel combustion biomass burning deforestation volatilization of fertilisers emission from livestock feedlots human sewage treatment plants ```
56
why is human growing of crops fixing more nitrogen into atmosphere
as they have symbiotic relationships with nitrogen0 fixing bacteria, increasing N2 fixation - oxygen taken but nitrogen released
57
what experiment is used to determine the optimal fertilizer regime for hay yield
the park grass experiment
58
for every ammonium ion taken up by plants, what is released into the soil
a hydrogen ion is released into the soil for every ammonium ion taken up by plants
59
what effect on the soil does inputs in the form of sodiumnitrate have
non acidifying
60
which fertilizer could you use that would be non acidifying
sodium nitrate
61
which fertilizer could you use that would be strongly acidifying
ammonium sulphate
62
what effect does adding ammonium sulphate as fertilizer have on soil
strongly acidifying
63
what effect does nitrogen deposition have on biodiversity
it reduces biodiversity
64
what effect have humans had on the rate of nitrogen input into the terrestrial nitrogen cycle
they have approx doubled it
65
what effect have humans had on N2O concentrations
increased it - drive the formation of photochemical smog over large regions of Earth
66
what causes the photochemical smog over large regions of Earth
increased conc of N2O and other nitrogen oxides
67
after nitrogen, what is the next most importent macronutrient
phosphorus
68
what is P required for
ADP/ATP production membranes nucleic acid
69
in which ecosystems does phosphorus limit Primary production
terrestrial ecosystems with old, well weathered soils like tropical lowland forests and some freshwater
70
what can phosphorus availability control the rate of
can control the rate of biological N2 fixation, due to its high metabolic demand for P
71
in what way are the C, P and N cycles linked to eachother
through photosynth, NPP, deocmposition and N2 fixation
72
what is Ps atmospheric pool
doesnt have one - dust
73
where are the largest pools of P
in terrestrial soils and marine sediments
74
how is P released from sedimentary rocks
by weathering
75
what is labile P
P that is either in dissolved form or is readily released into solution
76
what special techniques do plants have to get P
organic acid exudation mycorrhizae special root forms eg.proteoid roots
77
what are proteoid roots
plants have these roots to enable them to get P
78
why is P cycle more difficult to study compared to N cycle
it involves inorganic mineral reactions which tend to interfere with the availability of P in organic cycles + complicate measurement
79
what does occluded mean
stuck into clay particle
80
what bound forms of phosphorus exist
occluded and adsorbed P (adsorbed onto Fe and Al ions on clay surgace)
81
describe soil age effects
more highly weathered soils tend to be high in Al and Fe therefore P tends to get "locked" up as occluded/adsorbed
82
what nutrients do more highly weathered soils tend to be high in# what is the consequence of this
Al and Fe | P tends therefore to get locked up as it adsorbs onto Fe and Al ions on clay surfce
83
how much % of total soil P is available in older soil
less than 1 % of total soil P is available in older soils
84
which bound form of P is most tight
occluded P -probs gone for all time | adsorbed P is probs exchangable
85
which bound form of P is probs to some extent exchangable
adorbed P
86
what are TRFs limited in
P