Domain V: Disposition of Materials with Hazards Flashcards

1
Q

What does LDR mean under RCRA?

A

Land Disposal Restriction (LDR)

In 1984, Congress created land disposal restrictions program as part of the Hazardous and Solid Waste Amendments (HSWA) to the Resource conservation and recovery act (RCRA).

It requires the EPA to specify either concentration levels or methods of treatment for hazardous constituents to meet before land disposal.

The LDR program applies to both generators of hazardous waste and facilities that treat, store, or dispose of hazardous waste (TSDF facilities).

The foundation of the LDR program consists of 3 prohibitions:

1.) Disposal - the prohibition against land disposal of untreated hazardous waste
2.) Dilution - The dilution prohibition ensures that wastes are properly treated and not simply diluted
3.) Storage - The storage prohibition prevents the indefinite storage of hazardous waste in lieu of treatment

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2
Q

What are the requirements when a TSDF is closed?

A

When a hazardous waste management unit stops receiving waste at the end of its active life, it must be cleaned up, closed, monitored, and maintained in accordance with RCRA closure and post-closure care requirements.

TSDFs must also comply with both EPA regulations under RCRA and OSHA regulations under Hazardous Waste Operations and Emergency Response (HAZWOPER)

At TSDFs where multiple hazardous waste management units are in operations, one unit may cease operation. This is known as partial closure. The closed units are subject to all applicable closure requirements.

All TSDFs are required to prepare and submit a written closure plan. A permitted facility submits this plan as part of its permit application. Closure plans must be certified by an independent professional engineer.

Post-closure care is required for land disposal units that leave waste in place upon closure. These sites must have provisions to protect the surrounding environment and population from releases of hazardous constituents. the standard post-closure care period is 30 years.

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3
Q

What is the underground injection control program?

A

This program is found under the Safe Drinking Water Act (SDWA)

The Underground Injection Control program consists of six classes of injection wells. Each well class is based on the type and depth of the injection activity, and the potential for that injection activity to result in endangerment of a USDW.

No owner or operator shall construct, operate, maintain, convert, plig, abandon, or conduct any other injection activity in a manner that allows the movement of fluid containing any contaminant into underground sources of drinking water.

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4
Q

What is a Class I well under the Underground Injection Control Program?

A

Class I wells are used to inject hazardous and non-hazardous wastes into deep, isolated rock formations.

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5
Q

What is a Class II well under the Underground Injection Control Program?

A

Class II wells are used exclusively to inject fluids associated with oil and natural gas production.

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6
Q

What is a Class III well under the Underground Injection Control Program?

A

Class III wells are used to inject fluids to dissolve and extract minerals.

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7
Q

What is a Class IV well under the Underground Injection Control Program?

A

Class IV wells are shallow wells used to inject hazardous or radioactive wastes into or above a geologic formation that contains a USDW.

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8
Q

What is a Class V well under the Underground Injection Control Program?

A

Class V wells are used to inject non-hazardous fluids underground. Most Class V wells are used to dispose of wastes into or above underground sources of drinking water.

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9
Q

What is a Class VI well under the Underground Injection Control Program?

A

Class VI wells are wells used for injection of carbon dioxide (CO2) into underground subsurface rock formations for long-term storage, or geologic sequestration.

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10
Q

Are generators allowed to treat hazardous waste?

A

No.

A permit is required for any treatment of hazardous waste.

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11
Q

What are three desirable alternatives to immediate land burial of hazardous waste?

A

Resource Recovery

Detoxification

Volume reduction, coupled with disposal

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12
Q

Hazardous waste treatment processes can be classified into four general groups. What are they?

A

Chemical Treatment
This includes neutralization, precipitation, ion exchange, reduction, or oxidation, etc

Physical treatment
solidification, flotation, sedimentation, evaporation, or filtration, etc

Biological Treatment
landfarming, etc.

Thermal Treatment
incineration

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13
Q

Describe biological treatment of hazardous waste.

A

A treatment process in which bacteria, fungi, and or microorganisms are used to alter or destroy hazardous waste. Liquid and soil wastes that can be treated by this method may include toxic chlorinated and aromatic organic compounds. The process is highly sensitive to environmental conditions, including fluctuations in pH and temperature, and to changes in the concentrations of heavy metals and salts in the waste stream.

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14
Q

Describe chemical treatment of hazardous waste.

A

A treatment process in which the hazardous waste is altered by a chemical reaction in order to destroy the hazardous component. Waste that can be treated by this method include both organic and inorganic compounds without heavy metals. Drawbacks to this method include the inhibition of the treatment process reaction by impurities in the waste and the potential generation of hazardous byproducts.

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15
Q

Describe physical treatment of hazardous waste.

A

A treatment process in which the hazardous waste is separated from its carrier by various physical methods such as adsorption, distillation, filtration, etc. Physical treatment is applicable tp a wide variety of wastes but further treatment is usually required.

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16
Q

Describe stabilization, solidification, and encapsulation treatment of hazardous waste.

A

A treatment process which isolates hazardous wastes from the surrounding environment without destroying the hazardous constituents. The treatment objective is normally achieved by mixing the waste with an inorganic compounds such as fly ash, lime, clay, etc., to form a chemically and mechanically stable solid. The treated waste generally has higher strength, lower permeability, and lower leachability than the untreated waste. Stabilization/solidification/encapsulation treatment is applicable primarily to inorganic wastes containing heavy metals.

17
Q

What is thermal treatment of hazardous waste?

A

Thermal treatment is a treatment process involving the decomposition of hazardous waste by thermal means into les hazardous or nonhazardous components. When subjected to high temperatures (2500-3000F), organic wastes decompose to similar, less toxic forms. Complete combustion yields carbon dioxide and waster plus small amounts of carbon monoxide, nitrous oxides, and chlorine and bromine acid gases. Some thermal processes produce off-gases and ash that require further treatment or landfill disposal. Thermal treatment is most suitable for organic waste and is less effective when attempting to detoxify heavy metals and inorganic compounds. One drawback to thermal treatment is the high cost involved.

18
Q

The disposal of PCBs and Asbestos is controlled under which federal act(s)?

A

TSCA

Toxic Substances Control Act

The Toxic Substances Control Act of 1976 provides EPA with authority to require reporting, record-keeping and testing requirements, and restrictions relating to chemical substances and/or mixtures. Certain substances are generally excluded from TSCA, including, among others, food, drugs, cosmetics and pesticides.

TSCA addresses the production, importation, use, and disposal of specific chemicals including polychlorinated biphenyls (PCBs), asbestos, radon and lead-based paint.

19
Q

Farmers who dispose of their pesticides must comply with:

A

RCRA

Pesticides are regulated under Federal Insecticide, Fungicide, Rodenticide Act (FIFRA) until disposal. However, disposal of pesticides is regulated under the Resource Conservation and Recovery Act (RCRA).

20
Q

The operation of municipal non-hazardous wastes landfills is controlled by:

A

Subtitle D of RCRA

Non-hazardous solid waste sites (municipal landfills) are regulated under subtitle D of RCRA.

21
Q

Incinerators of hazardous waste in the United States are regulated inder:

A

Both RCRA and TSCA set regulatory requirements for incinerating hazardous wastes such as PCBs.

22
Q

The EPA’s recommended disposal procedure for asbestos is:

A

Landfill

Asbestos particles are not hazardous until they are airborne. The recommended procedure for disposal is landfill.