DAT Chem ch 7 Flashcards
solubility rule 1 (most of the ionic compounds that have any of the following are soluble in water
nitrate NO3- perchlorate ClO4- Acetate C2H3O2- Ammonium NH4+ and group 1 metal cations
solubility rule 2 ( most ionic compounds that have any of the following are insoluble in water water
Ag+ Pb2+ S2- OH- Hg22+ Po43-
when a ionic compounds has as insoluble and soluble element which wins?
the soluble
Net ionic equation Steps (summary
1) balance
2) use the solubility rule to label everything
3) cut all the aq in half separating their cation and anion (do not touch the insoluble) it cannot be separated
4) Cancel out all the species that are the same (these are the spectator ions)
Formula for solutions (concentrations)
molality = moles solute/kg of solvent molarity = moles of solute/ L of solution
as temp ____ the gas solubility ____
increase
decreases
as temp ____ the solids solubility _____
increases
increases
As pressure _____ the gas solubility ____
INCREASE
increases
Henry’s law
Pa=Kh[A}
Pa is the gas pressure in the solution
[A] is the gas concentration in moles per liter (molarity)
Kh is the constant that differs for each gas, solvent, and temp
What is colligative properties
properties of a solution that change as you add more solute
solute ____ = _____ freezing point
increase
decrease
Why?
the more solute you add in water, the harder it is for the water molecules to link together to become solid. so temp must increase even more for it to freeze
Solute _____ = _____ boiling point
increase
increase
Solute becomes a more organized state (lower entropy) when water evaporates due to high boiling point. It does not want a low entropy and is going to try to avoid being evaporated. causing the boiling point to increase to take it longer to evaporate
How to calculate freezing point?
just count the molecules bigger numebr wins Ex/ NaCl = 2 Na2So4 = 3 So Na2so4 wins
Raoults law
Pa= XaPpure Ppure= vapor pressure of the original solvent, when its pure Xa= percentage of solvent in the new solution Pa = solutions new vapor pressure
When to use raoults law
what amount a solution’s vapor pressure decrease, when a solute is added?