DAT Chem ch 7 Flashcards

1
Q

solubility rule 1 (most of the ionic compounds that have any of the following are soluble in water

A

nitrate NO3- perchlorate ClO4- Acetate C2H3O2- Ammonium NH4+ and group 1 metal cations

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2
Q

solubility rule 2 ( most ionic compounds that have any of the following are insoluble in water water

A

Ag+ Pb2+ S2- OH- Hg22+ Po43-

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3
Q

when a ionic compounds has as insoluble and soluble element which wins?

A

the soluble

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4
Q

Net ionic equation Steps (summary

A

1) balance
2) use the solubility rule to label everything
3) cut all the aq in half separating their cation and anion (do not touch the insoluble) it cannot be separated
4) Cancel out all the species that are the same (these are the spectator ions)

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5
Q

Formula for solutions (concentrations)

A
molality = moles solute/kg of solvent
molarity = moles of solute/ L of solution
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6
Q

as temp ____ the gas solubility ____

A

increase

decreases

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7
Q

as temp ____ the solids solubility _____

A

increases

increases

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8
Q

As pressure _____ the gas solubility ____

A

INCREASE

increases

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9
Q

Henry’s law

A

Pa=Kh[A}
Pa is the gas pressure in the solution
[A] is the gas concentration in moles per liter (molarity)
Kh is the constant that differs for each gas, solvent, and temp

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10
Q

What is colligative properties

A

properties of a solution that change as you add more solute

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11
Q

solute ____ = _____ freezing point

A

increase
decrease
Why?
the more solute you add in water, the harder it is for the water molecules to link together to become solid. so temp must increase even more for it to freeze

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12
Q

Solute _____ = _____ boiling point

A

increase
increase
Solute becomes a more organized state (lower entropy) when water evaporates due to high boiling point. It does not want a low entropy and is going to try to avoid being evaporated. causing the boiling point to increase to take it longer to evaporate

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13
Q

How to calculate freezing point?

A
just count the molecules
bigger numebr wins
Ex/ 
NaCl = 2 
Na2So4 = 3
So Na2so4 wins
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14
Q

Raoults law

A
Pa= XaPpure
Ppure= vapor pressure of the original solvent, when its pure
Xa= percentage of solvent in the new solution
Pa = solutions new vapor pressure
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15
Q

When to use raoults law

A

what amount a solution’s vapor pressure decrease, when a solute is added?

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16
Q

osmotic pressure formula

A
Pie= i MRT
Pie= osmotic pressure
i= vant hoff factor(how many things your molecules splits into
R= 0.0821
T= kelvin
17
Q

zero order reactions

A

plot is a straight line

decreased half life = decreased concentrations

18
Q

first order reactions

A

not a straight line
half life is constant
and is independent of concentration

19
Q

second order reactions

A

not a straight line

increased half life = decreased concentrations

20
Q

Collision theory

A

both molecules must collide
both must collide with enough energy
both must collide in the correct 3d orientation

21
Q

unsaturated

A

everything is dissolved

22
Q

saturated

A

not everything is dissolved