Core Definitions and Core Knowledge - AS level Flashcards

1
Q

Periodicity def

A

A repeated pattern or trend

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2
Q

Relative Atomic mass def

A

The relative atomic mass of an element is the average mass of its atoms, compared to 1/12th the mass of a carbon-12 atom

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3
Q

General formula def

A

formula for a family of compounds. E.g. alkanes‡ CnH2n+2 where n is the number of carbon atoms

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4
Q

Empirical formula def

A

shows the ratio of atoms in a compound. It is the simplest ratio in which atoms combine to form a compound

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5
Q

Molecular formula def

A

tells us how many of each type of atom there are in each molecule of the compound

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6
Q

Skeletal formula def

A

all the hydrogen atoms are removed from carbon chains, leaving just a carbon skeleton with functional groups attached to it

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7
Q

Displayed formula def

A

shows all the bonds in the molecule as individual lines (each line represents a pair of shared electrons)

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8
Q

Structural formula def

A

shows how the various atoms are bonded

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9
Q

Hydrated

A

A crystalline compound containing water molecules

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10
Q

Anhydrous def

A

A substance containing no water molecules

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11
Q

Water of crystallisation def

A

The water molecules bonded into a crystalline structure of a compound

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12
Q

How to improve results of water of crystallisation experiment

A
  • Use a mass balance that calculates to a greater number of decimal places to get a more accurate mass reading
  • Heat mixture until you record a constant mass
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13
Q

What happens if compound in water of crystallisation decomposes further?
How to stop this?

A
  • Anhydrous solid mass at end will be less than it should be

- You could heat it more gently, or take mixture off of heat

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14
Q

First ionisation energy

A

The energy required to remove one electron from each atom in one mole of gaseous atoms to produce one mole gaseous 1+ ions

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15
Q

Second ionisation energy

A

The energy required to remove one electron from each 1+ ion in one mole of gaseous 1+ ions to produce one mole of gaseous 2+ ions

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16
Q

Atomic number def

A

Number of protons in the nucleus

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17
Q

Orbital def

A

A region within an atom that can hold up to two electrons with opposite spin

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18
Q

What is meant by one mole of substance?

A
  • As many particles as there are carbon atoms in 12g of carbon - 12
  • Or: 6.02x10^23 atoms
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19
Q

How do London Forces arise?

A

-there is an uneven distribution of electrons present in molecule
↳ this creates an instantaneous dipole
-these cause induced dipoles in neighbouring molecules

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20
Q

Trend in boiling points of chlorine, bromine and iodine

A

H

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21
Q

Oxidising agent def

A

A substance that oxidises another substance by attracting its electrons and becoming reduced in the reaction itself(absorbs electrons from other substances)

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22
Q

Reducing agent def

A

A substance that reduces another substance in a reaction but becomes oxidised in the reaction itself(loses electrons, donates them)

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23
Q

Metallic bonding def

A

The electrostatic attraction between between cations and delocalised electrons

24
Q

Covalent bonding def

A

The electrostatic attraction between two atomic nuclei and a shared pair of electrons

25
Ionic bonding def
The electrostatic attraction between oppositely charged ions
26
Electronegativity def
The ability of an atom to attract a lone pair of electrons
27
Anomalous properties of water
- Adhesion/Surface Tension - Cohesion - Ice is less dense than water - water molecules are more spread apart by hydrogen bonds - High specific heat capacity - High latent heat of vaporisation
28
Radical definition
A species or element with an unpaired electron
29
What is meant by fractional distillation?
The separation of different hydrocarbons from crude oil by distillation due to different boiling points of each fraction
30
Methods for reducing pollution due to plastic/polymer disposal
- Make photodegradable polymers - Make biodegradable polymers - Combustion of the polymers to produce energy - Melt, reshape and remould the polymers for reuse - Used in feedstock for plastics and chemicals - Use waste polymers in organic feedstock - Use waste polymers in cracking
31
Atom economy def
(sum of) the molecular masses of the desired product ÷ sum of molecular masses of all reactants x 100 to get a percentage
32
Alkali def
A substance that releases OH- ions in solution
33
Acid def
A substance that releases H+ ions in solution
34
Standard solution def
A solution of known concentration
35
How to prepare a standard solution
H
36
Linear shape info
Bond angle: 180 Degrees 2 Bonded Pairs 0 Lone pairs
37
Non linear shape info
2BP At least one LP Bond angle less than 120 Degrees
38
Trigonal planar shape info
Bond angle: 120 Degrees | 3BP
39
Trigonal bipyramidal shape info
Bond angles: 120 and 90 Degrees | 5BP
40
Tetrahedral shape info
Bond angle: 109.5 Degrees | As long as 4BP and no LP
41
Octahedral shape info
Bond angle: 90 Degrees
42
Suggest two reasons why standard enthalpy changes of combustion determined experimentally are less exothermic than the calculated theoretical values.
- Conditions may have been non-standard - Heat may have been lost to the surroundings - Incomplete combustion(for standard enthalpy of combustion)
43
Bond angle of a molecule with 4BP and 0LP
109.5 Degrees
43
Bond angle of a molecule with 3BP and 1LP
107 Degrees
44
Bond angle of a molecule with 2BP and 2LP
104.5 Degrees
45
Standard Enthalpy Change of Formation def
The enthalpy change that takes place when 1 mole of a compound is formed from its constituent elements. All products and reactants are in standard states and conditions
46
Standard enthalpy change of combustion def
The enthalpy chnage that takes place when 1 mole of a compound reacts with oxygen and is completely burnt. All products and reactants formed under standard conditions in standard states
47
Standard Enthalpy change of neutralisation def
the enthalpy change associated with the formation of one mole of water from a reaction standard comditions and states
48
Standard enthalpy change of reaction def
the enthalpy change associated with a given reaction (in the molar quantities given in the equation)
49
Average bond enthalpy def
The average enthalpy change that takes place when breaking one mole of a given type of bond in the molecules of a gaseous species, by heterolytic fission,
50
Are bond enthalpy values positive of negative values?
Always positive | As energy is required/taken in to break the bonds
51
Why can enthalpy change of formation not be measured directly?
- Byproducts may be formed | - Activation energy is too high
52
Reflux Def
The continuous boiling and condensing of a reaction mixture to ensure the reaction takes place without boiling dry.
53
In Markownikoffs rule, explain why one product formed is in much greater quantity than the other organic product. (2 Marks)
The major product is the most stable carbocation formed | The most stable carbocation is the carbon that is bonded to the most carbon groups/atoms
54
Identify two potential disadvantages of using catalyst in industrial processes
Catalysts are expensive Cost - expensive to remove catalysts from reaction mixture and products Catalysts could be potentially toxic/harmful to humans