Condensation polymers Flashcards
What are condensation reactions?
Two molecules react together to form one larger molecule and one smaller molecule - often water
How are esters formed?
Carboxylic acids -COOH react with alcohols -OH to form organic compounds called esters and water ; the remaining parts of the Carboxylic acid and alcohol are joined by an -COO- ester group
Difference in monomers between addition polymerisation and condensation polymerisation
Addition - monomer molecules has one functional group C=C
Condensation - needs two different functional groups (one at each end of monomer)
Functional groups in amino acids
Amino group -NH2
Carboxylic group -COOH
Amino reacts with Carboxylic and the organic product formed still had an amino group and a Carboxylic group - so it can join more amino acids and this forms a long polymer molecule
REMAINING PARTS OF MONOMER JOINED BY AMIDE -CONH- GROUP
Polyesters
Made from a Carboxylic acid (2 -COOH groups) and an alcohol (2 -OH groups) ; contain many ester -COO- groups and PET is a polyester used to make clothing and fizzy drink bottles
Polyamide
Made from a Carboxylic acid (2 -COOH groups) and an amine (2 -NH2 amino groups) ; called polyamide because they contain many amide groups -CONH and nylon is a polyamide used to make clothing and carpets
Differences in process between addition and condensation polymerisation
Addition - catalyst and at high temperatures and pressures
Condensation - happens without a catalyst at room temperature and pressure (able to make nylon in school laboratory)