Class Three Flashcards
closed system
environment cannot contribute matter to it
isolated system
environment cannot contribute energy or matter
open system
environment is free to interact with the system
how can the total energy in a system change
if energy is transferred into or out of a system
temperature vs thermal energy
temperature = intensive
thermal energy = extensive
what is heat (q)
transfer of thermal energy between a system and its environment
what does the zeroth law of thermodynamics state
objects A and B = thermal equilibrium
objects B and C = thermal equilibrium
then A and C must be in equilibrium as well
kinetic energy and temperature equation
what is kb and when is it used
1.38 x 10-23 J/K
used when looking at the relationship with kinetic energy and temperature
three ways heat transfer occurs
conduction
convection
radiation
what conducts heat well
metals
what is convection
heat expanding + becoming less dense than surrounding air → heat rise
what is radiation
heat transfer by absorption of energy carried by light waves
as the temperature of materials increase..
they expand
first law of thermodynamics
total energy of the universe is constant → energy cannot be created or destroyed
equation for first law of thermodynamics
difference in E = Q - W
when is work (W) considered positive
when work is being done by the system on the environment
what is an isobaric process
one that occurs at constant pressure
what is an isochoric process
one that maintains a constant volume
is work done in isochoric processes
no
when does an isothermal process occur
when heat is allowed to pass freely between a system and its environment
in an isobaric process..
W = P (change in V)
in an isochoric process..
W = 0
change in E = Q
in an isothermal process..
change in E = 0
Q = W
what happens in an adiabatic process
no heat is transferred between the system and the environment (all energy is transferred as work)